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Poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(II)] monohydrate]

In the title coordination polymer, {[Ba(C(7)H(2)N(2)O(7))(H(2)O)(2)]·H(2)O}(n), the Ba(II) atom is ten-coordinated by seven O atoms from four 3,5-dinitro­salicylatate ligands, two μ(2)-bridging aqua ligands and one water mol­ecule. The coordination mode is best described as a bicapped square-anti­pr...

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Detalles Bibliográficos
Autores principales: Song, Wen-Dong, Fan, Run-Zhen, Gu, Chang-Sheng, Hao, Xiao-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960902/
https://www.ncbi.nlm.nih.gov/pubmed/21202008
http://dx.doi.org/10.1107/S1600536808006338
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author Song, Wen-Dong
Fan, Run-Zhen
Gu, Chang-Sheng
Hao, Xiao-Min
author_facet Song, Wen-Dong
Fan, Run-Zhen
Gu, Chang-Sheng
Hao, Xiao-Min
author_sort Song, Wen-Dong
collection PubMed
description In the title coordination polymer, {[Ba(C(7)H(2)N(2)O(7))(H(2)O)(2)]·H(2)O}(n), the Ba(II) atom is ten-coordinated by seven O atoms from four 3,5-dinitro­salicylatate ligands, two μ(2)-bridging aqua ligands and one water mol­ecule. The coordination mode is best described as a bicapped square-anti­prismatic geometry. The 3,5-dinitrosalicylatate ligands bridge three Ba atoms. Centrosymmetrically related dinuclear barium units, with a Ba⋯Ba separation of 4.767 (5) Å, form infinite chains, which are further self-assembled into a supra­molecular network through inter­molecular O—H⋯O hydrogen-bonding inter­actions between O atoms of 3,5-dinitro­salicylatate ligands and water mol­ecules.
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spelling pubmed-29609022010-12-30 Poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(II)] monohydrate] Song, Wen-Dong Fan, Run-Zhen Gu, Chang-Sheng Hao, Xiao-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ba(C(7)H(2)N(2)O(7))(H(2)O)(2)]·H(2)O}(n), the Ba(II) atom is ten-coordinated by seven O atoms from four 3,5-dinitro­salicylatate ligands, two μ(2)-bridging aqua ligands and one water mol­ecule. The coordination mode is best described as a bicapped square-anti­prismatic geometry. The 3,5-dinitrosalicylatate ligands bridge three Ba atoms. Centrosymmetrically related dinuclear barium units, with a Ba⋯Ba separation of 4.767 (5) Å, form infinite chains, which are further self-assembled into a supra­molecular network through inter­molecular O—H⋯O hydrogen-bonding inter­actions between O atoms of 3,5-dinitro­salicylatate ligands and water mol­ecules. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2960902/ /pubmed/21202008 http://dx.doi.org/10.1107/S1600536808006338 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Wen-Dong
Fan, Run-Zhen
Gu, Chang-Sheng
Hao, Xiao-Min
Poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(II)] monohydrate]
title Poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(II)] monohydrate]
title_full Poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(II)] monohydrate]
title_fullStr Poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(II)] monohydrate]
title_full_unstemmed Poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(II)] monohydrate]
title_short Poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(II)] monohydrate]
title_sort poly[[μ(2)-aqua-aqua­(μ(3)-3,5-dinitro­salicylato)barium(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960902/
https://www.ncbi.nlm.nih.gov/pubmed/21202008
http://dx.doi.org/10.1107/S1600536808006338
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