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Poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(II)] monohydrate]
In the title coordination polymer, {[Ba(C(7)H(2)N(2)O(7))(H(2)O)(2)]·H(2)O}(n), the Ba(II) atom is ten-coordinated by seven O atoms from four 3,5-dinitrosalicylatate ligands, two μ(2)-bridging aqua ligands and one water molecule. The coordination mode is best described as a bicapped square-antipr...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960902/ https://www.ncbi.nlm.nih.gov/pubmed/21202008 http://dx.doi.org/10.1107/S1600536808006338 |
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author | Song, Wen-Dong Fan, Run-Zhen Gu, Chang-Sheng Hao, Xiao-Min |
author_facet | Song, Wen-Dong Fan, Run-Zhen Gu, Chang-Sheng Hao, Xiao-Min |
author_sort | Song, Wen-Dong |
collection | PubMed |
description | In the title coordination polymer, {[Ba(C(7)H(2)N(2)O(7))(H(2)O)(2)]·H(2)O}(n), the Ba(II) atom is ten-coordinated by seven O atoms from four 3,5-dinitrosalicylatate ligands, two μ(2)-bridging aqua ligands and one water molecule. The coordination mode is best described as a bicapped square-antiprismatic geometry. The 3,5-dinitrosalicylatate ligands bridge three Ba atoms. Centrosymmetrically related dinuclear barium units, with a Ba⋯Ba separation of 4.767 (5) Å, form infinite chains, which are further self-assembled into a supramolecular network through intermolecular O—H⋯O hydrogen-bonding interactions between O atoms of 3,5-dinitrosalicylatate ligands and water molecules. |
format | Text |
id | pubmed-2960902 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29609022010-12-30 Poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(II)] monohydrate] Song, Wen-Dong Fan, Run-Zhen Gu, Chang-Sheng Hao, Xiao-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ba(C(7)H(2)N(2)O(7))(H(2)O)(2)]·H(2)O}(n), the Ba(II) atom is ten-coordinated by seven O atoms from four 3,5-dinitrosalicylatate ligands, two μ(2)-bridging aqua ligands and one water molecule. The coordination mode is best described as a bicapped square-antiprismatic geometry. The 3,5-dinitrosalicylatate ligands bridge three Ba atoms. Centrosymmetrically related dinuclear barium units, with a Ba⋯Ba separation of 4.767 (5) Å, form infinite chains, which are further self-assembled into a supramolecular network through intermolecular O—H⋯O hydrogen-bonding interactions between O atoms of 3,5-dinitrosalicylatate ligands and water molecules. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2960902/ /pubmed/21202008 http://dx.doi.org/10.1107/S1600536808006338 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Wen-Dong Fan, Run-Zhen Gu, Chang-Sheng Hao, Xiao-Min Poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(II)] monohydrate] |
title | Poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(II)] monohydrate] |
title_full | Poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(II)] monohydrate] |
title_fullStr | Poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(II)] monohydrate] |
title_full_unstemmed | Poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(II)] monohydrate] |
title_short | Poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(II)] monohydrate] |
title_sort | poly[[μ(2)-aqua-aqua(μ(3)-3,5-dinitrosalicylato)barium(ii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960902/ https://www.ncbi.nlm.nih.gov/pubmed/21202008 http://dx.doi.org/10.1107/S1600536808006338 |
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