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Alpinumisoflavone
The title compound, C(20)H(16)O(5), {systematic name: 5-hydroxy-7-(4-hydroxyphenyl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b′]dipyran-6-one}, was obtained by demethylation of the biologically active related compound, 4-O-methylalpinumisoflavone. The molecular structure of the title compound is c...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960904/ https://www.ncbi.nlm.nih.gov/pubmed/21202104 http://dx.doi.org/10.1107/S1600536808006867 |
Sumario: | The title compound, C(20)H(16)O(5), {systematic name: 5-hydroxy-7-(4-hydroxyphenyl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b′]dipyran-6-one}, was obtained by demethylation of the biologically active related compound, 4-O-methylalpinumisoflavone. The molecular structure of the title compound is characterized by a fused tricyclic system that contains an approximately planar benzopyrone ring fragment. The six membered pyran ring adopts a half-chair conformation. Both ring systems show an out-of-plane twist. The dihedral angle between the mean plane of the benzopyrone system and the benzene ring is 54.29 (3)°. The molecules are linked by O—H⋯O hydrogen bonds, forming a molecular tape running along the b axis. |
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