Cargando…
Alpinumisoflavone
The title compound, C(20)H(16)O(5), {systematic name: 5-hydroxy-7-(4-hydroxyphenyl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b′]dipyran-6-one}, was obtained by demethylation of the biologically active related compound, 4-O-methylalpinumisoflavone. The molecular structure of the title compound is c...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960904/ https://www.ncbi.nlm.nih.gov/pubmed/21202104 http://dx.doi.org/10.1107/S1600536808006867 |
_version_ | 1782188853632696320 |
---|---|
author | Harrison, Jerry Joe Ebow Kingsley Tabuchi, Youhei Ishida, Hiroyuki Kingsford-Adaboh, Robert |
author_facet | Harrison, Jerry Joe Ebow Kingsley Tabuchi, Youhei Ishida, Hiroyuki Kingsford-Adaboh, Robert |
author_sort | Harrison, Jerry Joe Ebow Kingsley |
collection | PubMed |
description | The title compound, C(20)H(16)O(5), {systematic name: 5-hydroxy-7-(4-hydroxyphenyl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b′]dipyran-6-one}, was obtained by demethylation of the biologically active related compound, 4-O-methylalpinumisoflavone. The molecular structure of the title compound is characterized by a fused tricyclic system that contains an approximately planar benzopyrone ring fragment. The six membered pyran ring adopts a half-chair conformation. Both ring systems show an out-of-plane twist. The dihedral angle between the mean plane of the benzopyrone system and the benzene ring is 54.29 (3)°. The molecules are linked by O—H⋯O hydrogen bonds, forming a molecular tape running along the b axis. |
format | Text |
id | pubmed-2960904 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29609042010-12-30 Alpinumisoflavone Harrison, Jerry Joe Ebow Kingsley Tabuchi, Youhei Ishida, Hiroyuki Kingsford-Adaboh, Robert Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(16)O(5), {systematic name: 5-hydroxy-7-(4-hydroxyphenyl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b′]dipyran-6-one}, was obtained by demethylation of the biologically active related compound, 4-O-methylalpinumisoflavone. The molecular structure of the title compound is characterized by a fused tricyclic system that contains an approximately planar benzopyrone ring fragment. The six membered pyran ring adopts a half-chair conformation. Both ring systems show an out-of-plane twist. The dihedral angle between the mean plane of the benzopyrone system and the benzene ring is 54.29 (3)°. The molecules are linked by O—H⋯O hydrogen bonds, forming a molecular tape running along the b axis. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2960904/ /pubmed/21202104 http://dx.doi.org/10.1107/S1600536808006867 Text en © Harrison et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Harrison, Jerry Joe Ebow Kingsley Tabuchi, Youhei Ishida, Hiroyuki Kingsford-Adaboh, Robert Alpinumisoflavone |
title | Alpinumisoflavone |
title_full | Alpinumisoflavone |
title_fullStr | Alpinumisoflavone |
title_full_unstemmed | Alpinumisoflavone |
title_short | Alpinumisoflavone |
title_sort | alpinumisoflavone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960904/ https://www.ncbi.nlm.nih.gov/pubmed/21202104 http://dx.doi.org/10.1107/S1600536808006867 |
work_keys_str_mv | AT harrisonjerryjoeebowkingsley alpinumisoflavone AT tabuchiyouhei alpinumisoflavone AT ishidahiroyuki alpinumisoflavone AT kingsfordadabohrobert alpinumisoflavone |