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Alpinumisoflavone

The title compound, C(20)H(16)O(5), {systematic name: 5-hydr­oxy-7-(4-hydroxy­phen­yl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b′]dipyran-6-one}, was obtained by demethyl­ation of the biologically active related compound, 4-O-methyl­alpinum­iso­flavone. The mol­ecular structure of the title compound is c...

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Detalles Bibliográficos
Autores principales: Harrison, Jerry Joe Ebow Kingsley, Tabuchi, Youhei, Ishida, Hiroyuki, Kingsford-Adaboh, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960904/
https://www.ncbi.nlm.nih.gov/pubmed/21202104
http://dx.doi.org/10.1107/S1600536808006867
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author Harrison, Jerry Joe Ebow Kingsley
Tabuchi, Youhei
Ishida, Hiroyuki
Kingsford-Adaboh, Robert
author_facet Harrison, Jerry Joe Ebow Kingsley
Tabuchi, Youhei
Ishida, Hiroyuki
Kingsford-Adaboh, Robert
author_sort Harrison, Jerry Joe Ebow Kingsley
collection PubMed
description The title compound, C(20)H(16)O(5), {systematic name: 5-hydr­oxy-7-(4-hydroxy­phen­yl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b′]dipyran-6-one}, was obtained by demethyl­ation of the biologically active related compound, 4-O-methyl­alpinum­iso­flavone. The mol­ecular structure of the title compound is characterized by a fused tricyclic system that contains an approximately planar benzopyrone ring fragment. The six membered pyran ring adopts a half-chair conformation. Both ring systems show an out-of-plane twist. The dihedral angle between the mean plane of the benzopyrone system and the benzene ring is 54.29 (3)°. The mol­ecules are linked by O—H⋯O hydrogen bonds, forming a mol­ecular tape running along the b axis.
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spelling pubmed-29609042010-12-30 Alpinumisoflavone Harrison, Jerry Joe Ebow Kingsley Tabuchi, Youhei Ishida, Hiroyuki Kingsford-Adaboh, Robert Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(16)O(5), {systematic name: 5-hydr­oxy-7-(4-hydroxy­phen­yl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b′]dipyran-6-one}, was obtained by demethyl­ation of the biologically active related compound, 4-O-methyl­alpinum­iso­flavone. The mol­ecular structure of the title compound is characterized by a fused tricyclic system that contains an approximately planar benzopyrone ring fragment. The six membered pyran ring adopts a half-chair conformation. Both ring systems show an out-of-plane twist. The dihedral angle between the mean plane of the benzopyrone system and the benzene ring is 54.29 (3)°. The mol­ecules are linked by O—H⋯O hydrogen bonds, forming a mol­ecular tape running along the b axis. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2960904/ /pubmed/21202104 http://dx.doi.org/10.1107/S1600536808006867 Text en © Harrison et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Harrison, Jerry Joe Ebow Kingsley
Tabuchi, Youhei
Ishida, Hiroyuki
Kingsford-Adaboh, Robert
Alpinumisoflavone
title Alpinumisoflavone
title_full Alpinumisoflavone
title_fullStr Alpinumisoflavone
title_full_unstemmed Alpinumisoflavone
title_short Alpinumisoflavone
title_sort alpinumisoflavone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960904/
https://www.ncbi.nlm.nih.gov/pubmed/21202104
http://dx.doi.org/10.1107/S1600536808006867
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