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Tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)]
In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluorobenzoate and one 1,10-phenanthroline ligands. Two cations are linked into a centrosymmetric dimer via three bridging carboxylate groups of 2,4-difluoro...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960912/ https://www.ncbi.nlm.nih.gov/pubmed/21201985 http://dx.doi.org/10.1107/S1600536808004431 |
| _version_ | 1782188855706779648 |
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| author | Wang, Shou-Bin He, Hong-Mei Li, Sheng Tang, Kun |
| author_facet | Wang, Shou-Bin He, Hong-Mei Li, Sheng Tang, Kun |
| author_sort | Wang, Shou-Bin |
| collection | PubMed |
| description | In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluorobenzoate and one 1,10-phenanthroline ligands. Two cations are linked into a centrosymmetric dimer via three bridging carboxylate groups of 2,4-difluorobenzoate ligands. Each Gd(3+) ion is nine-coordinated by seven O atoms and two N atoms. |
| format | Text |
| id | pubmed-2960912 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29609122010-12-30 Tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)] Wang, Shou-Bin He, Hong-Mei Li, Sheng Tang, Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluorobenzoate and one 1,10-phenanthroline ligands. Two cations are linked into a centrosymmetric dimer via three bridging carboxylate groups of 2,4-difluorobenzoate ligands. Each Gd(3+) ion is nine-coordinated by seven O atoms and two N atoms. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2960912/ /pubmed/21201985 http://dx.doi.org/10.1107/S1600536808004431 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Shou-Bin He, Hong-Mei Li, Sheng Tang, Kun Tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)] |
| title | Tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)] |
| title_full | Tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)] |
| title_fullStr | Tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)] |
| title_full_unstemmed | Tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)] |
| title_short | Tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(III)] |
| title_sort | tetrakis(μ-2,4-difluorobenzoato)bis[(2,4-difluorobenzoato)(1,10-phenanthroline)gadolinium(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960912/ https://www.ncbi.nlm.nih.gov/pubmed/21201985 http://dx.doi.org/10.1107/S1600536808004431 |
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