catena-Poly[[chloridocopper(II)]bis­(μ-3,3′,5,5′-tetra­methyl-4,4′-methylene­dipyrazole)[chloridocopper(II)]-di-μ-chlorido]

In the title compound, [Cu(2)Cl(4)(C(11)H(16)N(4))](n), the Cu atom is coordinated by two N atoms of two 3,3′,5,5′-tetra­methyl-4,4′-methyl­enedipyrazole (H(2)mbdpz) ligands, two bridging Cl atoms and one terminal Cl atom, forming a square-pyramidal geometry. The bridging Cl atoms and the bridging H...

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Detalles Bibliográficos
Autor principal: Wang, Zhi-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960916/
https://www.ncbi.nlm.nih.gov/pubmed/21202017
http://dx.doi.org/10.1107/S1600536808006909
Descripción
Sumario:In the title compound, [Cu(2)Cl(4)(C(11)H(16)N(4))](n), the Cu atom is coordinated by two N atoms of two 3,3′,5,5′-tetra­methyl-4,4′-methyl­enedipyrazole (H(2)mbdpz) ligands, two bridging Cl atoms and one terminal Cl atom, forming a square-pyramidal geometry. The bridging Cl atoms and the bridging H(2)mbdpz ligands connect the Cu atoms to build up an extended one-dimensional chain. The chains are further connected through N—H⋯Cl hydrogen bonds to build up a two-dimensional layer in the (011) plane. An inversion centre lies between every pair of adjacent Cu atoms.

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