2-(4,6-Dimethyl­pyrimidin-2-ylsulfan­yl)-N-phenyl­acetamide

In the title compound, C(14)H(15)N(3)OS, the phenyl ring is almost perpendicular to the dimethyl­pyrimidine group, with a dihedral angle of 88.1 (3)°. The Csp (2)—S bond of 1.759 (3) Å is significantly shorter than the Csp (3)—S bond of 1.795 (3) Å due to the p–π conjugation.

Detalles Bibliográficos
Autores principales: Gao, Li-Xin, Fang, Guang-Jun, Feng, Jin-Guo, Liang, Dong, Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960928/
https://www.ncbi.nlm.nih.gov/pubmed/21202149
http://dx.doi.org/10.1107/S1600536808007940
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author Gao, Li-Xin
Fang, Guang-Jun
Feng, Jin-Guo
Liang, Dong
Wang, Wei
author_facet Gao, Li-Xin
Fang, Guang-Jun
Feng, Jin-Guo
Liang, Dong
Wang, Wei
author_sort Gao, Li-Xin
collection PubMed
description In the title compound, C(14)H(15)N(3)OS, the phenyl ring is almost perpendicular to the dimethyl­pyrimidine group, with a dihedral angle of 88.1 (3)°. The Csp (2)—S bond of 1.759 (3) Å is significantly shorter than the Csp (3)—S bond of 1.795 (3) Å due to the p–π conjugation.
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spelling pubmed-29609282010-12-30 2-(4,6-Dimethyl­pyrimidin-2-ylsulfan­yl)-N-phenyl­acetamide Gao, Li-Xin Fang, Guang-Jun Feng, Jin-Guo Liang, Dong Wang, Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(15)N(3)OS, the phenyl ring is almost perpendicular to the dimethyl­pyrimidine group, with a dihedral angle of 88.1 (3)°. The Csp (2)—S bond of 1.759 (3) Å is significantly shorter than the Csp (3)—S bond of 1.795 (3) Å due to the p–π conjugation. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960928/ /pubmed/21202149 http://dx.doi.org/10.1107/S1600536808007940 Text en © Gao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Li-Xin
Fang, Guang-Jun
Feng, Jin-Guo
Liang, Dong
Wang, Wei
2-(4,6-Dimethyl­pyrimidin-2-ylsulfan­yl)-N-phenyl­acetamide
title 2-(4,6-Dimethyl­pyrimidin-2-ylsulfan­yl)-N-phenyl­acetamide
title_full 2-(4,6-Dimethyl­pyrimidin-2-ylsulfan­yl)-N-phenyl­acetamide
title_fullStr 2-(4,6-Dimethyl­pyrimidin-2-ylsulfan­yl)-N-phenyl­acetamide
title_full_unstemmed 2-(4,6-Dimethyl­pyrimidin-2-ylsulfan­yl)-N-phenyl­acetamide
title_short 2-(4,6-Dimethyl­pyrimidin-2-ylsulfan­yl)-N-phenyl­acetamide
title_sort 2-(4,6-dimethyl­pyrimidin-2-ylsulfan­yl)-n-phenyl­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960928/
https://www.ncbi.nlm.nih.gov/pubmed/21202149
http://dx.doi.org/10.1107/S1600536808007940
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AT liangdong 246dimethylpyrimidin2ylsulfanylnphenylacetamide
AT wangwei 246dimethylpyrimidin2ylsulfanylnphenylacetamide

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