catena-Poly[[[bis­(thio­urea-κS)copper(I)]-μ-thio­urea-κ(2) S:S] iodide acetonitrile hemisolvate]

The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thio­urea in acetonitrile. There are two independent Cu(I) ions in the asymmetric unit which are coordinated by two terminal and two bridging thio­urea ligands to form a one-dimensional helical chain struc...

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Detalles Bibliográficos
Autores principales: Jia, Li, Kong, Ling-Qian, Li, Da-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960929/
https://www.ncbi.nlm.nih.gov/pubmed/21202021
http://dx.doi.org/10.1107/S1600536808007265
Descripción
Sumario:The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thio­urea in acetonitrile. There are two independent Cu(I) ions in the asymmetric unit which are coordinated by two terminal and two bridging thio­urea ligands to form a one-dimensional helical chain structure progagating in the a-axis direction. Each Cu(I) ion is in a distorted tetra­hedral coordination environment. The crystal structure is stabilized by weak N—H⋯S and N—H⋯I hydrogen bonds.

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