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catena-Poly[[[bis(thiourea-κS)copper(I)]-μ-thiourea-κ(2) S:S] iodide acetonitrile hemisolvate]
The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thiourea in acetonitrile. There are two independent Cu(I) ions in the asymmetric unit which are coordinated by two terminal and two bridging thiourea ligands to form a one-dimensional helical chain struc...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960929/ https://www.ncbi.nlm.nih.gov/pubmed/21202021 http://dx.doi.org/10.1107/S1600536808007265 |
| _version_ | 1782188859966095360 |
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| author | Jia, Li Kong, Ling-Qian Li, Da-Cheng |
| author_facet | Jia, Li Kong, Ling-Qian Li, Da-Cheng |
| author_sort | Jia, Li |
| collection | PubMed |
| description | The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thiourea in acetonitrile. There are two independent Cu(I) ions in the asymmetric unit which are coordinated by two terminal and two bridging thiourea ligands to form a one-dimensional helical chain structure progagating in the a-axis direction. Each Cu(I) ion is in a distorted tetrahedral coordination environment. The crystal structure is stabilized by weak N—H⋯S and N—H⋯I hydrogen bonds. |
| format | Text |
| id | pubmed-2960929 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29609292010-12-30 catena-Poly[[[bis(thiourea-κS)copper(I)]-μ-thiourea-κ(2) S:S] iodide acetonitrile hemisolvate] Jia, Li Kong, Ling-Qian Li, Da-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, {[Cu(CH(4)N(2)S)(3)]I·0.5CH(3)CN}(n), was formed by the reaction of CuI and thiourea in acetonitrile. There are two independent Cu(I) ions in the asymmetric unit which are coordinated by two terminal and two bridging thiourea ligands to form a one-dimensional helical chain structure progagating in the a-axis direction. Each Cu(I) ion is in a distorted tetrahedral coordination environment. The crystal structure is stabilized by weak N—H⋯S and N—H⋯I hydrogen bonds. International Union of Crystallography 2008-03-20 /pmc/articles/PMC2960929/ /pubmed/21202021 http://dx.doi.org/10.1107/S1600536808007265 Text en © Jia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jia, Li Kong, Ling-Qian Li, Da-Cheng catena-Poly[[[bis(thiourea-κS)copper(I)]-μ-thiourea-κ(2) S:S] iodide acetonitrile hemisolvate] |
| title |
catena-Poly[[[bis(thiourea-κS)copper(I)]-μ-thiourea-κ(2)
S:S] iodide acetonitrile hemisolvate] |
| title_full |
catena-Poly[[[bis(thiourea-κS)copper(I)]-μ-thiourea-κ(2)
S:S] iodide acetonitrile hemisolvate] |
| title_fullStr |
catena-Poly[[[bis(thiourea-κS)copper(I)]-μ-thiourea-κ(2)
S:S] iodide acetonitrile hemisolvate] |
| title_full_unstemmed |
catena-Poly[[[bis(thiourea-κS)copper(I)]-μ-thiourea-κ(2)
S:S] iodide acetonitrile hemisolvate] |
| title_short |
catena-Poly[[[bis(thiourea-κS)copper(I)]-μ-thiourea-κ(2)
S:S] iodide acetonitrile hemisolvate] |
| title_sort | catena-poly[[[bis(thiourea-κs)copper(i)]-μ-thiourea-κ(2)
s:s] iodide acetonitrile hemisolvate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960929/ https://www.ncbi.nlm.nih.gov/pubmed/21202021 http://dx.doi.org/10.1107/S1600536808007265 |
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