Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II)

The potential tridentate Schiff base ligand 2-[1-(2-pyridyl­methyl­imino)eth­yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl­pyrrole with 2-amino­methyl­pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl­amine as a b...

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Detalles Bibliográficos
Autores principales: Li, Rongqing, Zhao, Pusu, Tang, Guodong, Tao, Yujia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960930/
https://www.ncbi.nlm.nih.gov/pubmed/21202015
http://dx.doi.org/10.1107/S1600536808006934
Descripción
Sumario:The potential tridentate Schiff base ligand 2-[1-(2-pyridyl­methyl­imino)eth­yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl­pyrrole with 2-amino­methyl­pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl­amine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N(3)Cl coordination.

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