Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II)

The potential tridentate Schiff base ligand 2-[1-(2-pyridyl­methyl­imino)eth­yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl­pyrrole with 2-amino­methyl­pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl­amine as a b...

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Detalles Bibliográficos
Autores principales: Li, Rongqing, Zhao, Pusu, Tang, Guodong, Tao, Yujia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960930/
https://www.ncbi.nlm.nih.gov/pubmed/21202015
http://dx.doi.org/10.1107/S1600536808006934
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author Li, Rongqing
Zhao, Pusu
Tang, Guodong
Tao, Yujia
author_facet Li, Rongqing
Zhao, Pusu
Tang, Guodong
Tao, Yujia
author_sort Li, Rongqing
collection PubMed
description The potential tridentate Schiff base ligand 2-[1-(2-pyridyl­methyl­imino)eth­yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl­pyrrole with 2-amino­methyl­pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl­amine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N(3)Cl coordination.
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spelling pubmed-29609302010-12-30 Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II) Li, Rongqing Zhao, Pusu Tang, Guodong Tao, Yujia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The potential tridentate Schiff base ligand 2-[1-(2-pyridyl­methyl­imino)eth­yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl­pyrrole with 2-amino­methyl­pyridine. The title compound, [Cu(C(12)H(12)N(3))Cl], was synthesized from HL and copper(II) chloride using triethyl­amine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N(3)Cl coordination. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2960930/ /pubmed/21202015 http://dx.doi.org/10.1107/S1600536808006934 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Rongqing
Zhao, Pusu
Tang, Guodong
Tao, Yujia
Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II)
title Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II)
title_full Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II)
title_fullStr Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II)
title_full_unstemmed Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II)
title_short Chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) N,N′,N′′}copper(II)
title_sort chlorido{2-[1-(2-pyridylmethyl­imino)eth­yl]pyrrolato-κ(3) n,n′,n′′}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960930/
https://www.ncbi.nlm.nih.gov/pubmed/21202015
http://dx.doi.org/10.1107/S1600536808006934
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AT zhaopusu chlorido212pyridylmethyliminoethylpyrrolatok3nnncopperii
AT tangguodong chlorido212pyridylmethyliminoethylpyrrolatok3nnncopperii
AT taoyujia chlorido212pyridylmethyliminoethylpyrrolatok3nnncopperii

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