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4-[(E)-2-Ferrocenylethenyl]-1,8-naphthalic anhydride
In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed through π–π interactions [centr...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960931/ https://www.ncbi.nlm.nih.gov/pubmed/21202023 http://dx.doi.org/10.1107/S1600536808007393 |
Sumario: | In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed through π–π interactions [centroid–centroid distance = 3.624 (2) Å] between the substituted ferrocene ring and the three fused rings of the naphthalic anhydride unit. Pairs of dimers are held together by further naphthalene–naphthalene π–π interactions [distance between parallel mean planes 3.45 (3) Å]. Each dimer interacts with four neighbouring dimers in a herringbone fashion through C—H⋯π interactions, so forming a two-dimensional sheet-like structure. |
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