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4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride

In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed through π–π inter­actions [centr...

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Detalles Bibliográficos
Autores principales: Munro, Natasha H., Hanton, Lyall R., McAdam, C. John, McMorran, David A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960931/
https://www.ncbi.nlm.nih.gov/pubmed/21202023
http://dx.doi.org/10.1107/S1600536808007393
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author Munro, Natasha H.
Hanton, Lyall R.
McAdam, C. John
McMorran, David A.
author_facet Munro, Natasha H.
Hanton, Lyall R.
McAdam, C. John
McMorran, David A.
author_sort Munro, Natasha H.
collection PubMed
description In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed through π–π inter­actions [centroid–centroid distance = 3.624 (2) Å] between the substituted ferrocene ring and the three fused rings of the naphthalic anhydride unit. Pairs of dimers are held together by further naphthalene–naphthalene π–π interactions [distance between parallel mean planes 3.45 (3) Å]. Each dimer inter­acts with four neighbouring dimers in a herringbone fashion through C—H⋯π inter­actions, so forming a two-dimensional sheet-like structure.
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spelling pubmed-29609312010-12-30 4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride Munro, Natasha H. Hanton, Lyall R. McAdam, C. John McMorran, David A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6)° with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed through π–π inter­actions [centroid–centroid distance = 3.624 (2) Å] between the substituted ferrocene ring and the three fused rings of the naphthalic anhydride unit. Pairs of dimers are held together by further naphthalene–naphthalene π–π interactions [distance between parallel mean planes 3.45 (3) Å]. Each dimer inter­acts with four neighbouring dimers in a herringbone fashion through C—H⋯π inter­actions, so forming a two-dimensional sheet-like structure. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960931/ /pubmed/21202023 http://dx.doi.org/10.1107/S1600536808007393 Text en © Munro et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Munro, Natasha H.
Hanton, Lyall R.
McAdam, C. John
McMorran, David A.
4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride
title 4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride
title_full 4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride
title_fullStr 4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride
title_full_unstemmed 4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride
title_short 4-[(E)-2-Ferrocenylethen­yl]-1,8-naphthalic anhydride
title_sort 4-[(e)-2-ferrocenylethen­yl]-1,8-naphthalic anhydride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960931/
https://www.ncbi.nlm.nih.gov/pubmed/21202023
http://dx.doi.org/10.1107/S1600536808007393
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