[(2S)-2-(3,5-Dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) O,N,O′](dimethyl­formamide-κO)copper(II)

In the title complex, [Cu(C(16)H(11)Cl(2)NO(4))(C(3)H(7)NO)] , the Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L (2−) {LH(2) = (2S)-[2-(3,5-dichloro-2-hydroxy­benzyl­idene)­imino]-3-(4-hydroxy­phenyl)propionic acid} and one O atom from a dimethyl­formamide mol...

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Detalles Bibliográficos
Autores principales: Tan, Ming-Xiong, Chen, Zhen-Feng, Neng, Zhou, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960937/
https://www.ncbi.nlm.nih.gov/pubmed/21202043
http://dx.doi.org/10.1107/S1600536808007939
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author Tan, Ming-Xiong
Chen, Zhen-Feng
Neng, Zhou
Liang, Hong
author_facet Tan, Ming-Xiong
Chen, Zhen-Feng
Neng, Zhou
Liang, Hong
author_sort Tan, Ming-Xiong
collection PubMed
description In the title complex, [Cu(C(16)H(11)Cl(2)NO(4))(C(3)H(7)NO)] , the Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L (2−) {LH(2) = (2S)-[2-(3,5-dichloro-2-hydroxy­benzyl­idene)­imino]-3-(4-hydroxy­phenyl)propionic acid} and one O atom from a dimethyl­formamide mol­ecule, resulting in a slightly distorted square-planar geometry. The structure forms a one-dimensional chain through weak coordination bonds [Cu⋯O 3.080 (1), Cu⋯Cl 3.269 (1) Å] and a three-dimensional network through O—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-29609372010-12-30 [(2S)-2-(3,5-Dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) O,N,O′](dimethyl­formamide-κO)copper(II) Tan, Ming-Xiong Chen, Zhen-Feng Neng, Zhou Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(16)H(11)Cl(2)NO(4))(C(3)H(7)NO)] , the Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L (2−) {LH(2) = (2S)-[2-(3,5-dichloro-2-hydroxy­benzyl­idene)­imino]-3-(4-hydroxy­phenyl)propionic acid} and one O atom from a dimethyl­formamide mol­ecule, resulting in a slightly distorted square-planar geometry. The structure forms a one-dimensional chain through weak coordination bonds [Cu⋯O 3.080 (1), Cu⋯Cl 3.269 (1) Å] and a three-dimensional network through O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960937/ /pubmed/21202043 http://dx.doi.org/10.1107/S1600536808007939 Text en © Tan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Ming-Xiong
Chen, Zhen-Feng
Neng, Zhou
Liang, Hong
[(2S)-2-(3,5-Dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) O,N,O′](dimethyl­formamide-κO)copper(II)
title [(2S)-2-(3,5-Dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) O,N,O′](dimethyl­formamide-κO)copper(II)
title_full [(2S)-2-(3,5-Dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) O,N,O′](dimethyl­formamide-κO)copper(II)
title_fullStr [(2S)-2-(3,5-Dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) O,N,O′](dimethyl­formamide-κO)copper(II)
title_full_unstemmed [(2S)-2-(3,5-Dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) O,N,O′](dimethyl­formamide-κO)copper(II)
title_short [(2S)-2-(3,5-Dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) O,N,O′](dimethyl­formamide-κO)copper(II)
title_sort [(2s)-2-(3,5-dichloro-2-oxidobenzyl­ideneamino)-3-(4-hydroxy­phen­yl)propionato-κ(3) o,n,o′](dimethyl­formamide-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960937/
https://www.ncbi.nlm.nih.gov/pubmed/21202043
http://dx.doi.org/10.1107/S1600536808007939
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