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4-{2-[(5-Chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide
In the molecule of the title compound, C(15)H(15)ClN(2)O(3)S, the S atom adopts a distorted tetrahedral coordination geometry with two O atoms, one N atom of the amide group and one C atom of the aromatic ring. An intramolecular O—H⋯N hydrogen bond results in the formation of a planar six-membere...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960939/ https://www.ncbi.nlm.nih.gov/pubmed/21202115 http://dx.doi.org/10.1107/S1600536808005084 |
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author | Chohan, Zahid H. Shad, Hazoor A. Tahir, M. Nawaz Khan, Islam Ullah |
author_facet | Chohan, Zahid H. Shad, Hazoor A. Tahir, M. Nawaz Khan, Islam Ullah |
author_sort | Chohan, Zahid H. |
collection | PubMed |
description | In the molecule of the title compound, C(15)H(15)ClN(2)O(3)S, the S atom adopts a distorted tetrahedral coordination geometry with two O atoms, one N atom of the amide group and one C atom of the aromatic ring. An intramolecular O—H⋯N hydrogen bond results in the formation of a planar six-membered ring, which is oriented with respect to the adjacent aromatic ring at a dihedral angle of 3.38 (11)°. Thus, the two rings are nearly coplanar. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. |
format | Text |
id | pubmed-2960939 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29609392010-12-30 4-{2-[(5-Chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide Chohan, Zahid H. Shad, Hazoor A. Tahir, M. Nawaz Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(15)H(15)ClN(2)O(3)S, the S atom adopts a distorted tetrahedral coordination geometry with two O atoms, one N atom of the amide group and one C atom of the aromatic ring. An intramolecular O—H⋯N hydrogen bond results in the formation of a planar six-membered ring, which is oriented with respect to the adjacent aromatic ring at a dihedral angle of 3.38 (11)°. Thus, the two rings are nearly coplanar. In the crystal structure, intermolecular N—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. International Union of Crystallography 2008-03-20 /pmc/articles/PMC2960939/ /pubmed/21202115 http://dx.doi.org/10.1107/S1600536808005084 Text en © Chohan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chohan, Zahid H. Shad, Hazoor A. Tahir, M. Nawaz Khan, Islam Ullah 4-{2-[(5-Chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide |
title | 4-{2-[(5-Chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide |
title_full | 4-{2-[(5-Chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide |
title_fullStr | 4-{2-[(5-Chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide |
title_full_unstemmed | 4-{2-[(5-Chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide |
title_short | 4-{2-[(5-Chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide |
title_sort | 4-{2-[(5-chloro-2-hydroxybenzylidene)amino]ethyl}benzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960939/ https://www.ncbi.nlm.nih.gov/pubmed/21202115 http://dx.doi.org/10.1107/S1600536808005084 |
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