Cargando…

{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate

In the title dinuclear complex, [NiPr(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol ligands, forming a slightly distorted octa­hedral geometry. The Pr(III) ion is coordinated by six O atom...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Fei, Zhang, Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960940/
https://www.ncbi.nlm.nih.gov/pubmed/21202036
http://dx.doi.org/10.1107/S1600536808005357
_version_ 1782188862556078080
author Liu, Fei
Zhang, Fang
author_facet Liu, Fei
Zhang, Fang
author_sort Liu, Fei
collection PubMed
description In the title dinuclear complex, [NiPr(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol ligands, forming a slightly distorted octa­hedral geometry. The Pr(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a distorted bicapped square-anti­prismatic environment. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds connect complex mol­ecules and methanol solvent mol­ecules to form (10[Image: see text]) sheets.
format Text
id pubmed-2960940
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29609402010-12-30 {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate Liu, Fei Zhang, Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [NiPr(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol ligands, forming a slightly distorted octa­hedral geometry. The Pr(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a distorted bicapped square-anti­prismatic environment. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds connect complex mol­ecules and methanol solvent mol­ecules to form (10[Image: see text]) sheets. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960940/ /pubmed/21202036 http://dx.doi.org/10.1107/S1600536808005357 Text en © Liu and Zhang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Fei
Zhang, Fang
{μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate
title {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate
title_full {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate
title_fullStr {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate
title_full_unstemmed {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate
title_short {μ-6,6′-Dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate
title_sort {μ-6,6′-dimeth­oxy-2,2′-[propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}dimethanoltrinitratonickel(ii)praseodymium(iii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960940/
https://www.ncbi.nlm.nih.gov/pubmed/21202036
http://dx.doi.org/10.1107/S1600536808005357
work_keys_str_mv AT liufei m66dimethoxy22propane13diylbisnitrilomethylidynediphenolatodimethanoltrinitratonickeliipraseodymiumiiimethanoldisolvate
AT zhangfang m66dimethoxy22propane13diylbisnitrilomethylidynediphenolatodimethanoltrinitratonickeliipraseodymiumiiimethanoldisolvate