2-Thienylcarbonylmethylene–triphenylphosphorane ylide

In the mol­ecule of the title compound, (2-thienylcarbon­yl)(triphenyl­phospho­nio)methanide, C(24)H(19)OPS, the geometry around the P atom is nearly tetra­hedral and the O—C—C—P torsion angle is 2.80 (3)°. The thio­phene ring is twisted through an angle of 4.33 (4)° with respect to the plane of the...

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Detalles Bibliográficos
Autores principales: Sabounchei, Seyyed Javad, Jodaian, Vida, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960945/
https://www.ncbi.nlm.nih.gov/pubmed/21202045
http://dx.doi.org/10.1107/S1600536808005497
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author Sabounchei, Seyyed Javad
Jodaian, Vida
Khavasi, Hamid Reza
author_facet Sabounchei, Seyyed Javad
Jodaian, Vida
Khavasi, Hamid Reza
author_sort Sabounchei, Seyyed Javad
collection PubMed
description In the mol­ecule of the title compound, (2-thienylcarbon­yl)(triphenyl­phospho­nio)methanide, C(24)H(19)OPS, the geometry around the P atom is nearly tetra­hedral and the O—C—C—P torsion angle is 2.80 (3)°. The thio­phene ring is twisted through an angle of 4.33 (4)° with respect to the plane of the carbonyl group. Inter- and intra­molecular hydrogen bonds and C—H⋯π inter­actions are present in the crystal structure.
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spelling pubmed-29609452010-12-30 2-Thienylcarbonylmethylene–triphenylphosphorane ylide Sabounchei, Seyyed Javad Jodaian, Vida Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, (2-thienylcarbon­yl)(triphenyl­phospho­nio)methanide, C(24)H(19)OPS, the geometry around the P atom is nearly tetra­hedral and the O—C—C—P torsion angle is 2.80 (3)°. The thio­phene ring is twisted through an angle of 4.33 (4)° with respect to the plane of the carbonyl group. Inter- and intra­molecular hydrogen bonds and C—H⋯π inter­actions are present in the crystal structure. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2960945/ /pubmed/21202045 http://dx.doi.org/10.1107/S1600536808005497 Text en © Sabounchei et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sabounchei, Seyyed Javad
Jodaian, Vida
Khavasi, Hamid Reza
2-Thienylcarbonylmethylene–triphenylphosphorane ylide
title 2-Thienylcarbonylmethylene–triphenylphosphorane ylide
title_full 2-Thienylcarbonylmethylene–triphenylphosphorane ylide
title_fullStr 2-Thienylcarbonylmethylene–triphenylphosphorane ylide
title_full_unstemmed 2-Thienylcarbonylmethylene–triphenylphosphorane ylide
title_short 2-Thienylcarbonylmethylene–triphenylphosphorane ylide
title_sort 2-thienylcarbonylmethylene–triphenylphosphorane ylide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960945/
https://www.ncbi.nlm.nih.gov/pubmed/21202045
http://dx.doi.org/10.1107/S1600536808005497
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AT jodaianvida 2thienylcarbonylmethylenetriphenylphosphoraneylide
AT khavasihamidreza 2thienylcarbonylmethylenetriphenylphosphoraneylide

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