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4-(5-Chloro-2-hydroxy­benzyl­idene­amino)-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide

The title compound, C(19)H(17)ClN(4)O(3)S, is a Schiff base compound of 5-chloro­salicylaldehyde and sulfamethazine [4-amino-N-(4,6-dimethyl-2-pyrimidin­yl)benzene­sulfonamide]. The geometry around the S atom is distorted tetra­hedral, comprising two O atoms of the sulfonyl group, a C atom of a benz...

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Detalles Bibliográficos
Autores principales: Chohan, Zahid H., Tahir, M. Nawaz, Shad, Hazoor A., Khan, Islam Ullah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960946/
https://www.ncbi.nlm.nih.gov/pubmed/21202046
http://dx.doi.org/10.1107/S1600536808005606
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author Chohan, Zahid H.
Tahir, M. Nawaz
Shad, Hazoor A.
Khan, Islam Ullah
author_facet Chohan, Zahid H.
Tahir, M. Nawaz
Shad, Hazoor A.
Khan, Islam Ullah
author_sort Chohan, Zahid H.
collection PubMed
description The title compound, C(19)H(17)ClN(4)O(3)S, is a Schiff base compound of 5-chloro­salicylaldehyde and sulfamethazine [4-amino-N-(4,6-dimethyl-2-pyrimidin­yl)benzene­sulfonamide]. The geometry around the S atom is distorted tetra­hedral, comprising two O atoms of the sulfonyl group, a C atom of a benzene ring and the amino N atom. The title compound has an intra­molecular O—H⋯N hydrogen bond and two inter­molecular C—H⋯O and N—H⋯O hydrogen bonds, which link neighbouring mol­ecules into 10-membered rings. As a result of an unavoidable conformational arrangement, a slightly short intra­molecular contact of distance 2.59 Å exists between an O atom of the sulfonyl group and an H atom of the sulfamethazine benzene ring.
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spelling pubmed-29609462010-12-30 4-(5-Chloro-2-hydroxy­benzyl­idene­amino)-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide Chohan, Zahid H. Tahir, M. Nawaz Shad, Hazoor A. Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(17)ClN(4)O(3)S, is a Schiff base compound of 5-chloro­salicylaldehyde and sulfamethazine [4-amino-N-(4,6-dimethyl-2-pyrimidin­yl)benzene­sulfonamide]. The geometry around the S atom is distorted tetra­hedral, comprising two O atoms of the sulfonyl group, a C atom of a benzene ring and the amino N atom. The title compound has an intra­molecular O—H⋯N hydrogen bond and two inter­molecular C—H⋯O and N—H⋯O hydrogen bonds, which link neighbouring mol­ecules into 10-membered rings. As a result of an unavoidable conformational arrangement, a slightly short intra­molecular contact of distance 2.59 Å exists between an O atom of the sulfonyl group and an H atom of the sulfamethazine benzene ring. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2960946/ /pubmed/21202046 http://dx.doi.org/10.1107/S1600536808005606 Text en © Chohan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chohan, Zahid H.
Tahir, M. Nawaz
Shad, Hazoor A.
Khan, Islam Ullah
4-(5-Chloro-2-hydroxy­benzyl­idene­amino)-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide
title 4-(5-Chloro-2-hydroxy­benzyl­idene­amino)-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide
title_full 4-(5-Chloro-2-hydroxy­benzyl­idene­amino)-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide
title_fullStr 4-(5-Chloro-2-hydroxy­benzyl­idene­amino)-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide
title_full_unstemmed 4-(5-Chloro-2-hydroxy­benzyl­idene­amino)-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide
title_short 4-(5-Chloro-2-hydroxy­benzyl­idene­amino)-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide
title_sort 4-(5-chloro-2-hydroxy­benzyl­idene­amino)-n-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960946/
https://www.ncbi.nlm.nih.gov/pubmed/21202046
http://dx.doi.org/10.1107/S1600536808005606
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