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4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide
The title compound, C(19)H(17)ClN(4)O(3)S, is a Schiff base compound of 5-chlorosalicylaldehyde and sulfamethazine [4-amino-N-(4,6-dimethyl-2-pyrimidinyl)benzenesulfonamide]. The geometry around the S atom is distorted tetrahedral, comprising two O atoms of the sulfonyl group, a C atom of a benz...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960946/ https://www.ncbi.nlm.nih.gov/pubmed/21202046 http://dx.doi.org/10.1107/S1600536808005606 |
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author | Chohan, Zahid H. Tahir, M. Nawaz Shad, Hazoor A. Khan, Islam Ullah |
author_facet | Chohan, Zahid H. Tahir, M. Nawaz Shad, Hazoor A. Khan, Islam Ullah |
author_sort | Chohan, Zahid H. |
collection | PubMed |
description | The title compound, C(19)H(17)ClN(4)O(3)S, is a Schiff base compound of 5-chlorosalicylaldehyde and sulfamethazine [4-amino-N-(4,6-dimethyl-2-pyrimidinyl)benzenesulfonamide]. The geometry around the S atom is distorted tetrahedral, comprising two O atoms of the sulfonyl group, a C atom of a benzene ring and the amino N atom. The title compound has an intramolecular O—H⋯N hydrogen bond and two intermolecular C—H⋯O and N—H⋯O hydrogen bonds, which link neighbouring molecules into 10-membered rings. As a result of an unavoidable conformational arrangement, a slightly short intramolecular contact of distance 2.59 Å exists between an O atom of the sulfonyl group and an H atom of the sulfamethazine benzene ring. |
format | Text |
id | pubmed-2960946 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29609462010-12-30 4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide Chohan, Zahid H. Tahir, M. Nawaz Shad, Hazoor A. Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(17)ClN(4)O(3)S, is a Schiff base compound of 5-chlorosalicylaldehyde and sulfamethazine [4-amino-N-(4,6-dimethyl-2-pyrimidinyl)benzenesulfonamide]. The geometry around the S atom is distorted tetrahedral, comprising two O atoms of the sulfonyl group, a C atom of a benzene ring and the amino N atom. The title compound has an intramolecular O—H⋯N hydrogen bond and two intermolecular C—H⋯O and N—H⋯O hydrogen bonds, which link neighbouring molecules into 10-membered rings. As a result of an unavoidable conformational arrangement, a slightly short intramolecular contact of distance 2.59 Å exists between an O atom of the sulfonyl group and an H atom of the sulfamethazine benzene ring. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2960946/ /pubmed/21202046 http://dx.doi.org/10.1107/S1600536808005606 Text en © Chohan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chohan, Zahid H. Tahir, M. Nawaz Shad, Hazoor A. Khan, Islam Ullah 4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide |
title | 4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide |
title_full | 4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide |
title_fullStr | 4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide |
title_full_unstemmed | 4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide |
title_short | 4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide |
title_sort | 4-(5-chloro-2-hydroxybenzylideneamino)-n-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960946/ https://www.ncbi.nlm.nih.gov/pubmed/21202046 http://dx.doi.org/10.1107/S1600536808005606 |
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