(Pyridino-15-crown-5-κ(5) N,O,O′,O′′,O′′′)bis­(thio­cyanato-κN)manganese(II)

The title complex, [Mn(NCS)(2)(C(13)H(19)NO(4))] {systematic name: [3,6,9,12-tetra­oxa-18-aza­bicyclo­[12.3.1]octa­cosa-14(18),15,17-triene-κ(5) N,O,O′,O′′,O′′′]bis­(thio­cyanato-κN)manganese(I­I)}, was obtained by the reaction of MnCl(2)·4H(2)O and NaSCN with pyridino-15-crown-5. The Mn(2+) center...

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Detalles Bibliográficos
Autores principales: Li, Chengjuan, Feng, Zejing, Li, Dacheng, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960950/
https://www.ncbi.nlm.nih.gov/pubmed/21202013
http://dx.doi.org/10.1107/S160053680800679X
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author Li, Chengjuan
Feng, Zejing
Li, Dacheng
Wang, Daqi
author_facet Li, Chengjuan
Feng, Zejing
Li, Dacheng
Wang, Daqi
author_sort Li, Chengjuan
collection PubMed
description The title complex, [Mn(NCS)(2)(C(13)H(19)NO(4))] {systematic name: [3,6,9,12-tetra­oxa-18-aza­bicyclo­[12.3.1]octa­cosa-14(18),15,17-triene-κ(5) N,O,O′,O′′,O′′′]bis­(thio­cyanato-κN)manganese(I­I)}, was obtained by the reaction of MnCl(2)·4H(2)O and NaSCN with pyridino-15-crown-5. The Mn(2+) center has a distorted penta­gonal bipyramidal coordination geometry, coordinated by four O atoms and one N atom of the pyridino-15-crown-5 mol­ecule, and by the N atoms of the two NCS(−) ligands.
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spelling pubmed-29609502010-12-30 (Pyridino-15-crown-5-κ(5) N,O,O′,O′′,O′′′)bis­(thio­cyanato-κN)manganese(II) Li, Chengjuan Feng, Zejing Li, Dacheng Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mn(NCS)(2)(C(13)H(19)NO(4))] {systematic name: [3,6,9,12-tetra­oxa-18-aza­bicyclo­[12.3.1]octa­cosa-14(18),15,17-triene-κ(5) N,O,O′,O′′,O′′′]bis­(thio­cyanato-κN)manganese(I­I)}, was obtained by the reaction of MnCl(2)·4H(2)O and NaSCN with pyridino-15-crown-5. The Mn(2+) center has a distorted penta­gonal bipyramidal coordination geometry, coordinated by four O atoms and one N atom of the pyridino-15-crown-5 mol­ecule, and by the N atoms of the two NCS(−) ligands. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2960950/ /pubmed/21202013 http://dx.doi.org/10.1107/S160053680800679X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Li, Chengjuan
Feng, Zejing
Li, Dacheng
Wang, Daqi
(Pyridino-15-crown-5-κ(5) N,O,O′,O′′,O′′′)bis­(thio­cyanato-κN)manganese(II)
title (Pyridino-15-crown-5-κ(5) N,O,O′,O′′,O′′′)bis­(thio­cyanato-κN)manganese(II)
title_full (Pyridino-15-crown-5-κ(5) N,O,O′,O′′,O′′′)bis­(thio­cyanato-κN)manganese(II)
title_fullStr (Pyridino-15-crown-5-κ(5) N,O,O′,O′′,O′′′)bis­(thio­cyanato-κN)manganese(II)
title_full_unstemmed (Pyridino-15-crown-5-κ(5) N,O,O′,O′′,O′′′)bis­(thio­cyanato-κN)manganese(II)
title_short (Pyridino-15-crown-5-κ(5) N,O,O′,O′′,O′′′)bis­(thio­cyanato-κN)manganese(II)
title_sort (pyridino-15-crown-5-κ(5) n,o,o′,o′′,o′′′)bis­(thio­cyanato-κn)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960950/
https://www.ncbi.nlm.nih.gov/pubmed/21202013
http://dx.doi.org/10.1107/S160053680800679X
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AT lidacheng pyridino15crown5k5noooobisthiocyanatoknmanganeseii
AT wangdaqi pyridino15crown5k5noooobisthiocyanatoknmanganeseii

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