Di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(I)]

The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å. Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry aro...

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Detalles Bibliográficos
Autores principales: Yamagata, Tsuneaki, Nakajima, Koji, Arimitsu, Kenji, Iseki, Aika, Tani, Kazuhide
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960958/
https://www.ncbi.nlm.nih.gov/pubmed/21202029
http://dx.doi.org/10.1107/S1600536808007216
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author Yamagata, Tsuneaki
Nakajima, Koji
Arimitsu, Kenji
Iseki, Aika
Tani, Kazuhide
author_facet Yamagata, Tsuneaki
Nakajima, Koji
Arimitsu, Kenji
Iseki, Aika
Tani, Kazuhide
author_sort Yamagata, Tsuneaki
collection PubMed
description The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å. Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar.
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spelling pubmed-29609582010-12-30 Di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(I)] Yamagata, Tsuneaki Nakajima, Koji Arimitsu, Kenji Iseki, Aika Tani, Kazuhide Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å. Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960958/ /pubmed/21202029 http://dx.doi.org/10.1107/S1600536808007216 Text en © Yamagata et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yamagata, Tsuneaki
Nakajima, Koji
Arimitsu, Kenji
Iseki, Aika
Tani, Kazuhide
Di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(I)]
title Di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(I)]
title_full Di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(I)]
title_fullStr Di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(I)]
title_full_unstemmed Di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(I)]
title_short Di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(I)]
title_sort di-μ-chlorido-bis­[bis­(η(2)-cyclo­octene)iridium(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960958/
https://www.ncbi.nlm.nih.gov/pubmed/21202029
http://dx.doi.org/10.1107/S1600536808007216
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AT nakajimakoji dimchloridobisbisē2cycloocteneiridiumi
AT arimitsukenji dimchloridobisbisē2cycloocteneiridiumi
AT isekiaika dimchloridobisbisē2cycloocteneiridiumi
AT tanikazuhide dimchloridobisbisē2cycloocteneiridiumi

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