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catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2) N (7):N (9)] hydroxide]

The title complex, {[Ni(C(7)H(7)N(4)O(2))]OH}(n), has been prepared through hydro­thermal synthesis. The asymmetric unit contains one [Ni(TH)](+) cation (TH is the theophylline anion) and one hydroxide anion. The Ni(2+) ion is coordinated by two N atoms from two neighboring theophylline anions. The...

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Detalles Bibliográficos
Autor principal: Wei, Lin-Heng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960965/
https://www.ncbi.nlm.nih.gov/pubmed/21202028
http://dx.doi.org/10.1107/S160053680800737X
Descripción
Sumario:The title complex, {[Ni(C(7)H(7)N(4)O(2))]OH}(n), has been prepared through hydro­thermal synthesis. The asymmetric unit contains one [Ni(TH)](+) cation (TH is the theophylline anion) and one hydroxide anion. The Ni(2+) ion is coordinated by two N atoms from two neighboring theophylline anions. The alternating linkage of the Ni(2+) cation and theophylline anion results in a one-dimensional chain along the [010] direction. Intermolec­ular O—H⋯O hydrogen bonds are present n the crystal structure.