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catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2) N (7):N (9)] hydroxide]
The title complex, {[Ni(C(7)H(7)N(4)O(2))]OH}(n), has been prepared through hydrothermal synthesis. The asymmetric unit contains one [Ni(TH)](+) cation (TH is the theophylline anion) and one hydroxide anion. The Ni(2+) ion is coordinated by two N atoms from two neighboring theophylline anions. The...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960965/ https://www.ncbi.nlm.nih.gov/pubmed/21202028 http://dx.doi.org/10.1107/S160053680800737X |
Sumario: | The title complex, {[Ni(C(7)H(7)N(4)O(2))]OH}(n), has been prepared through hydrothermal synthesis. The asymmetric unit contains one [Ni(TH)](+) cation (TH is the theophylline anion) and one hydroxide anion. The Ni(2+) ion is coordinated by two N atoms from two neighboring theophylline anions. The alternating linkage of the Ni(2+) cation and theophylline anion results in a one-dimensional chain along the [010] direction. Intermolecular O—H⋯O hydrogen bonds are present n the crystal structure. |
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