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catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2) N (7):N (9)] hydroxide]
The title complex, {[Ni(C(7)H(7)N(4)O(2))]OH}(n), has been prepared through hydrothermal synthesis. The asymmetric unit contains one [Ni(TH)](+) cation (TH is the theophylline anion) and one hydroxide anion. The Ni(2+) ion is coordinated by two N atoms from two neighboring theophylline anions. The...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960965/ https://www.ncbi.nlm.nih.gov/pubmed/21202028 http://dx.doi.org/10.1107/S160053680800737X |
| _version_ | 1782188868579098624 |
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| author | Wei, Lin-Heng |
| author_facet | Wei, Lin-Heng |
| author_sort | Wei, Lin-Heng |
| collection | PubMed |
| description | The title complex, {[Ni(C(7)H(7)N(4)O(2))]OH}(n), has been prepared through hydrothermal synthesis. The asymmetric unit contains one [Ni(TH)](+) cation (TH is the theophylline anion) and one hydroxide anion. The Ni(2+) ion is coordinated by two N atoms from two neighboring theophylline anions. The alternating linkage of the Ni(2+) cation and theophylline anion results in a one-dimensional chain along the [010] direction. Intermolecular O—H⋯O hydrogen bonds are present n the crystal structure. |
| format | Text |
| id | pubmed-2960965 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29609652010-12-30 catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2) N (7):N (9)] hydroxide] Wei, Lin-Heng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, {[Ni(C(7)H(7)N(4)O(2))]OH}(n), has been prepared through hydrothermal synthesis. The asymmetric unit contains one [Ni(TH)](+) cation (TH is the theophylline anion) and one hydroxide anion. The Ni(2+) ion is coordinated by two N atoms from two neighboring theophylline anions. The alternating linkage of the Ni(2+) cation and theophylline anion results in a one-dimensional chain along the [010] direction. Intermolecular O—H⋯O hydrogen bonds are present n the crystal structure. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960965/ /pubmed/21202028 http://dx.doi.org/10.1107/S160053680800737X Text en © Lin-Heng Wei 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wei, Lin-Heng catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2) N (7):N (9)] hydroxide] |
| title |
catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2)
N
(7):N
(9)] hydroxide] |
| title_full |
catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2)
N
(7):N
(9)] hydroxide] |
| title_fullStr |
catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2)
N
(7):N
(9)] hydroxide] |
| title_full_unstemmed |
catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2)
N
(7):N
(9)] hydroxide] |
| title_short |
catena-Poly[[nickel(II)-μ-1,3-dimethyl-2,6-dioxo-7H-purinato-κ(2)
N
(7):N
(9)] hydroxide] |
| title_sort | catena-poly[[nickel(ii)-μ-1,3-dimethyl-2,6-dioxo-7h-purinato-κ(2)
n
(7):n
(9)] hydroxide] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960965/ https://www.ncbi.nlm.nih.gov/pubmed/21202028 http://dx.doi.org/10.1107/S160053680800737X |
| work_keys_str_mv | AT weilinheng catenapolynickeliim13dimethyl26dioxo7hpurinatok2n7n9hydroxide |