4,6-Bis(diphenyl­phosphino)phenoxazine (nixantphos)

The title compound, C(36)H(27)NOP(2), has been reported as a ligand on rhodium for the catalysis of hydro­formyl­ation reactions. The key feature of the compound is the intra­molecular P⋯P distance of 4.255 (2) Å. The bond angles at the P atoms range from 99.93 (10) to 103.02 (10)°. The phenoxazine...

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Detalles Bibliográficos
Autores principales: Marimuthu, Thashree, Bala, Muhammad D., Friedrich, Holger B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960967/
https://www.ncbi.nlm.nih.gov/pubmed/21202102
http://dx.doi.org/10.1107/S1600536808006648
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author Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
author_facet Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
author_sort Marimuthu, Thashree
collection PubMed
description The title compound, C(36)H(27)NOP(2), has been reported as a ligand on rhodium for the catalysis of hydro­formyl­ation reactions. The key feature of the compound is the intra­molecular P⋯P distance of 4.255 (2) Å. The bond angles at the P atoms range from 99.93 (10) to 103.02 (10)°. The phenoxazine ring system is essentially planar and a non-crystallographic mirror plane through the N⋯O vector bis­ects the mol­ecule. The C—O bond lengths range from 1.388 (2) to 1.392 (2) Å and the C—N bond lengths range from 1.398 (3) to 1.403 (3) Å.
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spelling pubmed-29609672010-12-30 4,6-Bis(diphenyl­phosphino)phenoxazine (nixantphos) Marimuthu, Thashree Bala, Muhammad D. Friedrich, Holger B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(36)H(27)NOP(2), has been reported as a ligand on rhodium for the catalysis of hydro­formyl­ation reactions. The key feature of the compound is the intra­molecular P⋯P distance of 4.255 (2) Å. The bond angles at the P atoms range from 99.93 (10) to 103.02 (10)°. The phenoxazine ring system is essentially planar and a non-crystallographic mirror plane through the N⋯O vector bis­ects the mol­ecule. The C—O bond lengths range from 1.388 (2) to 1.392 (2) Å and the C—N bond lengths range from 1.398 (3) to 1.403 (3) Å. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2960967/ /pubmed/21202102 http://dx.doi.org/10.1107/S1600536808006648 Text en © Marimuthu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
4,6-Bis(diphenyl­phosphino)phenoxazine (nixantphos)
title 4,6-Bis(diphenyl­phosphino)phenoxazine (nixantphos)
title_full 4,6-Bis(diphenyl­phosphino)phenoxazine (nixantphos)
title_fullStr 4,6-Bis(diphenyl­phosphino)phenoxazine (nixantphos)
title_full_unstemmed 4,6-Bis(diphenyl­phosphino)phenoxazine (nixantphos)
title_short 4,6-Bis(diphenyl­phosphino)phenoxazine (nixantphos)
title_sort 4,6-bis(diphenyl­phosphino)phenoxazine (nixantphos)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960967/
https://www.ncbi.nlm.nih.gov/pubmed/21202102
http://dx.doi.org/10.1107/S1600536808006648
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AT friedrichholgerb 46bisdiphenylphosphinophenoxazinenixantphos

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