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Chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate
In the title complex, [Mn(C(22)H(18)N(2)O(2))Cl]·H(2)O, the Mn(III) center is in a distorted square-pyramidal configuration, with the N(2)O(2) dianionic tetradentate Schiff base ligand in the basal plane and the chloride ion in the apical position. The dihedral angle between the two outer phenolate...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960973/ https://www.ncbi.nlm.nih.gov/pubmed/21201996 http://dx.doi.org/10.1107/S160053680800620X |
| _version_ | 1782188870580830208 |
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| author | Eltayeb, Naser Eltaher Teoh, Siang Guan Chantrapromma, Suchada Fun, Hoong-Kun Adnan, Rohana |
| author_facet | Eltayeb, Naser Eltaher Teoh, Siang Guan Chantrapromma, Suchada Fun, Hoong-Kun Adnan, Rohana |
| author_sort | Eltayeb, Naser Eltaher |
| collection | PubMed |
| description | In the title complex, [Mn(C(22)H(18)N(2)O(2))Cl]·H(2)O, the Mn(III) center is in a distorted square-pyramidal configuration, with the N(2)O(2) dianionic tetradentate Schiff base ligand in the basal plane and the chloride ion in the apical position. The dihedral angle between the two outer phenolate rings of the tetradentate ligand is 8.25 (8)°. The central benzene ring makes dihedral angles of 4.31 (8) and 7.37 (8)° with the two outer phenolate rings. The water molecule links to the complex via an O—H⋯Cl hydrogen bond. In addition, in the crystal structure, weak C—H⋯O interactions link the molecules into infinite one-dimensional chains along [010]. The crystal is further stabilized by O—H⋯O and O—H⋯Cl hydrogen bonds, together with weak C—H⋯π interactions |
| format | Text |
| id | pubmed-2960973 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29609732010-12-30 Chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate Eltayeb, Naser Eltaher Teoh, Siang Guan Chantrapromma, Suchada Fun, Hoong-Kun Adnan, Rohana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(22)H(18)N(2)O(2))Cl]·H(2)O, the Mn(III) center is in a distorted square-pyramidal configuration, with the N(2)O(2) dianionic tetradentate Schiff base ligand in the basal plane and the chloride ion in the apical position. The dihedral angle between the two outer phenolate rings of the tetradentate ligand is 8.25 (8)°. The central benzene ring makes dihedral angles of 4.31 (8) and 7.37 (8)° with the two outer phenolate rings. The water molecule links to the complex via an O—H⋯Cl hydrogen bond. In addition, in the crystal structure, weak C—H⋯O interactions link the molecules into infinite one-dimensional chains along [010]. The crystal is further stabilized by O—H⋯O and O—H⋯Cl hydrogen bonds, together with weak C—H⋯π interactions International Union of Crystallography 2008-03-12 /pmc/articles/PMC2960973/ /pubmed/21201996 http://dx.doi.org/10.1107/S160053680800620X Text en © Eltayeb et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Eltayeb, Naser Eltaher Teoh, Siang Guan Chantrapromma, Suchada Fun, Hoong-Kun Adnan, Rohana Chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}manganese(III) monohydrate |
| title | Chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}manganese(III) monohydrate |
| title_full | Chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}manganese(III) monohydrate |
| title_fullStr | Chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}manganese(III) monohydrate |
| title_full_unstemmed | Chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}manganese(III) monohydrate |
| title_short | Chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}manganese(III) monohydrate |
| title_sort | chlorido{6,6′-dimethyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
o,n,n′,o′}manganese(iii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960973/ https://www.ncbi.nlm.nih.gov/pubmed/21201996 http://dx.doi.org/10.1107/S160053680800620X |
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