2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid

The title compound, C(14)H(12)N(4)O(2), a new N,O,N′-tridentate ligand, is V-shaped with the mean plane through the benzotriazole system [planar to within 0.013 (2) Å] inclined by 67.7 (1)° to the mean plane through the benzene ring. In the mol­ecule there is an intra­molecular N—H⋯O hydrogen bond i...

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Detalles Bibliográficos
Autores principales: Wang, Yao, Yin, Mai-Hua, Zhang, Guo-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960979/
https://www.ncbi.nlm.nih.gov/pubmed/21202125
http://dx.doi.org/10.1107/S160053680800740X
Descripción
Sumario:The title compound, C(14)H(12)N(4)O(2), a new N,O,N′-tridentate ligand, is V-shaped with the mean plane through the benzotriazole system [planar to within 0.013 (2) Å] inclined by 67.7 (1)° to the mean plane through the benzene ring. In the mol­ecule there is an intra­molecular N—H⋯O hydrogen bond involving the amine H atom and the carbonyl O atom. In the crystal structure, symmtry-related mol­ecules are connected by inter­molecular O—H⋯N and C—H⋯O hydrogen bonds and C—H⋯π inter­actions.

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