2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid

The title compound, C(14)H(12)N(4)O(2), a new N,O,N′-tridentate ligand, is V-shaped with the mean plane through the benzotriazole system [planar to within 0.013 (2) Å] inclined by 67.7 (1)° to the mean plane through the benzene ring. In the mol­ecule there is an intra­molecular N—H⋯O hydrogen bond i...

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Detalles Bibliográficos
Autores principales: Wang, Yao, Yin, Mai-Hua, Zhang, Guo-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960979/
https://www.ncbi.nlm.nih.gov/pubmed/21202125
http://dx.doi.org/10.1107/S160053680800740X
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author Wang, Yao
Yin, Mai-Hua
Zhang, Guo-Fang
author_facet Wang, Yao
Yin, Mai-Hua
Zhang, Guo-Fang
author_sort Wang, Yao
collection PubMed
description The title compound, C(14)H(12)N(4)O(2), a new N,O,N′-tridentate ligand, is V-shaped with the mean plane through the benzotriazole system [planar to within 0.013 (2) Å] inclined by 67.7 (1)° to the mean plane through the benzene ring. In the mol­ecule there is an intra­molecular N—H⋯O hydrogen bond involving the amine H atom and the carbonyl O atom. In the crystal structure, symmtry-related mol­ecules are connected by inter­molecular O—H⋯N and C—H⋯O hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-29609792010-12-30 2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid Wang, Yao Yin, Mai-Hua Zhang, Guo-Fang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(12)N(4)O(2), a new N,O,N′-tridentate ligand, is V-shaped with the mean plane through the benzotriazole system [planar to within 0.013 (2) Å] inclined by 67.7 (1)° to the mean plane through the benzene ring. In the mol­ecule there is an intra­molecular N—H⋯O hydrogen bond involving the amine H atom and the carbonyl O atom. In the crystal structure, symmtry-related mol­ecules are connected by inter­molecular O—H⋯N and C—H⋯O hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2008-03-20 /pmc/articles/PMC2960979/ /pubmed/21202125 http://dx.doi.org/10.1107/S160053680800740X Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Yao
Yin, Mai-Hua
Zhang, Guo-Fang
2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid
title 2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid
title_full 2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid
title_fullStr 2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid
title_full_unstemmed 2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid
title_short 2-(Benzotriazol-1-ylmethyl­amino)­benzoic acid
title_sort 2-(benzotriazol-1-ylmethyl­amino)­benzoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960979/
https://www.ncbi.nlm.nih.gov/pubmed/21202125
http://dx.doi.org/10.1107/S160053680800740X
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AT yinmaihua 2benzotriazol1ylmethylaminobenzoicacid
AT zhangguofang 2benzotriazol1ylmethylaminobenzoicacid

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