Bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate

The title compound, 2C(4)H(12)N(2) (2+)·C(10)H(2)O(8) (4−)·6H(2)O or (pipzH(2))(2)(btc)·6H(2)O, was formed from the reaction between benzene-1,2,4,5-tetra­carboxylic acid (btcH(4)) as a proton donor and piperazine (pipz) as a proton acceptor. A variety of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, as we...

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Detalles Bibliográficos
Autores principales: Aghabozorg, Hossein, Manteghi, Faranak, Ghadermazi, Mohammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960987/
https://www.ncbi.nlm.nih.gov/pubmed/21202130
http://dx.doi.org/10.1107/S1600536808007332
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author Aghabozorg, Hossein
Manteghi, Faranak
Ghadermazi, Mohammad
author_facet Aghabozorg, Hossein
Manteghi, Faranak
Ghadermazi, Mohammad
author_sort Aghabozorg, Hossein
collection PubMed
description The title compound, 2C(4)H(12)N(2) (2+)·C(10)H(2)O(8) (4−)·6H(2)O or (pipzH(2))(2)(btc)·6H(2)O, was formed from the reaction between benzene-1,2,4,5-tetra­carboxylic acid (btcH(4)) as a proton donor and piperazine (pipz) as a proton acceptor. A variety of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, as well as C—H⋯π inter­actions, are present in the crystal structure. Two water O atoms are each disordered over two positions; for both the site occupany factors are ca 0.66 and 0.34.
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spelling pubmed-29609872010-12-30 Bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate Aghabozorg, Hossein Manteghi, Faranak Ghadermazi, Mohammad Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 2C(4)H(12)N(2) (2+)·C(10)H(2)O(8) (4−)·6H(2)O or (pipzH(2))(2)(btc)·6H(2)O, was formed from the reaction between benzene-1,2,4,5-tetra­carboxylic acid (btcH(4)) as a proton donor and piperazine (pipz) as a proton acceptor. A variety of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, as well as C—H⋯π inter­actions, are present in the crystal structure. Two water O atoms are each disordered over two positions; for both the site occupany factors are ca 0.66 and 0.34. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960987/ /pubmed/21202130 http://dx.doi.org/10.1107/S1600536808007332 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Aghabozorg, Hossein
Manteghi, Faranak
Ghadermazi, Mohammad
Bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate
title Bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate
title_full Bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate
title_fullStr Bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate
title_full_unstemmed Bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate
title_short Bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate
title_sort bis(piperazinediium) benzene-1,2,4,5-tetra­carboxyl­ate hexa­hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960987/
https://www.ncbi.nlm.nih.gov/pubmed/21202130
http://dx.doi.org/10.1107/S1600536808007332
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