1-Hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane

In the title fused-ring compound, C(12)H(13)NO(3), the two five-membered C(3)NO rings both approximate to envelope conformations with C atoms in the flap positions. The OH group of the pendant CH(2)OH unit is disordered over two positions in a 0.528 (5):0.472 (5) ratio. One of the OH groups particip...

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Detalles Bibliográficos
Autores principales: Tai, Xi-Shi, Feng, Yi-Min, Kong, Fan-Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960989/
https://www.ncbi.nlm.nih.gov/pubmed/21202146
http://dx.doi.org/10.1107/S1600536808007976
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author Tai, Xi-Shi
Feng, Yi-Min
Kong, Fan-Yuan
author_facet Tai, Xi-Shi
Feng, Yi-Min
Kong, Fan-Yuan
author_sort Tai, Xi-Shi
collection PubMed
description In the title fused-ring compound, C(12)H(13)NO(3), the two five-membered C(3)NO rings both approximate to envelope conformations with C atoms in the flap positions. The OH group of the pendant CH(2)OH unit is disordered over two positions in a 0.528 (5):0.472 (5) ratio. One of the OH groups participates in an O—H⋯N hydrogen bond, generating centrosymmetric dimers in the crystal structure.
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spelling pubmed-29609892010-12-30 1-Hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane Tai, Xi-Shi Feng, Yi-Min Kong, Fan-Yuan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title fused-ring compound, C(12)H(13)NO(3), the two five-membered C(3)NO rings both approximate to envelope conformations with C atoms in the flap positions. The OH group of the pendant CH(2)OH unit is disordered over two positions in a 0.528 (5):0.472 (5) ratio. One of the OH groups participates in an O—H⋯N hydrogen bond, generating centrosymmetric dimers in the crystal structure. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960989/ /pubmed/21202146 http://dx.doi.org/10.1107/S1600536808007976 Text en © Tai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tai, Xi-Shi
Feng, Yi-Min
Kong, Fan-Yuan
1-Hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane
title 1-Hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane
title_full 1-Hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane
title_fullStr 1-Hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane
title_full_unstemmed 1-Hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane
title_short 1-Hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane
title_sort 1-hydroxymethyl-3,12-dioxa-14-aza­tetracyclo[9.2.1.0(4,14).0(5,10)]tetradecane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960989/
https://www.ncbi.nlm.nih.gov/pubmed/21202146
http://dx.doi.org/10.1107/S1600536808007976
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