The galla[1]ferrocenophane {[dimeth­yl(2-pyrid­yl)sil­yl]bis­(trimethyl­silyl)methyl-κ(2) C,N}(ferrocene-1,1′-di­yl)gallium(III)

The title compound, [GaFe(C(5)H(4))(2)(C(14)H(28)NSi(3))] or [{(2-H(4)C(5)N)Me(2)Si}(Me(3)Si)(2)C]Ga(C(5)H(4))(2)Fe, a galla[1]ferrocenophane, crystallizes with two independent mol­ecules in the asymmetric unit. In these strained sandwich compounds, the angles between the planes of the two π-ligands...

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Detalles Bibliográficos
Autores principales: Schachner, Jörg A., Quail, J. Wilson, Müller, Jens
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960990/
https://www.ncbi.nlm.nih.gov/pubmed/21201986
http://dx.doi.org/10.1107/S1600536808005503
Descripción
Sumario:The title compound, [GaFe(C(5)H(4))(2)(C(14)H(28)NSi(3))] or [{(2-H(4)C(5)N)Me(2)Si}(Me(3)Si)(2)C]Ga(C(5)H(4))(2)Fe, a galla[1]ferrocenophane, crystallizes with two independent mol­ecules in the asymmetric unit. In these strained sandwich compounds, the angles between the planes of the two π-ligands are 15.4 (2) and 16.4 (2)°, with gallium in a distorted tetrahedral coordination environment.

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