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The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2) C,N}(ferrocene-1,1′-diyl)gallium(III)
The title compound, [GaFe(C(5)H(4))(2)(C(14)H(28)NSi(3))] or [{(2-H(4)C(5)N)Me(2)Si}(Me(3)Si)(2)C]Ga(C(5)H(4))(2)Fe, a galla[1]ferrocenophane, crystallizes with two independent molecules in the asymmetric unit. In these strained sandwich compounds, the angles between the planes of the two π-ligands...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960990/ https://www.ncbi.nlm.nih.gov/pubmed/21201986 http://dx.doi.org/10.1107/S1600536808005503 |
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| author | Schachner, Jörg A. Quail, J. Wilson Müller, Jens |
| author_facet | Schachner, Jörg A. Quail, J. Wilson Müller, Jens |
| author_sort | Schachner, Jörg A. |
| collection | PubMed |
| description | The title compound, [GaFe(C(5)H(4))(2)(C(14)H(28)NSi(3))] or [{(2-H(4)C(5)N)Me(2)Si}(Me(3)Si)(2)C]Ga(C(5)H(4))(2)Fe, a galla[1]ferrocenophane, crystallizes with two independent molecules in the asymmetric unit. In these strained sandwich compounds, the angles between the planes of the two π-ligands are 15.4 (2) and 16.4 (2)°, with gallium in a distorted tetrahedral coordination environment. |
| format | Text |
| id | pubmed-2960990 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29609902010-12-30 The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2) C,N}(ferrocene-1,1′-diyl)gallium(III) Schachner, Jörg A. Quail, J. Wilson Müller, Jens Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [GaFe(C(5)H(4))(2)(C(14)H(28)NSi(3))] or [{(2-H(4)C(5)N)Me(2)Si}(Me(3)Si)(2)C]Ga(C(5)H(4))(2)Fe, a galla[1]ferrocenophane, crystallizes with two independent molecules in the asymmetric unit. In these strained sandwich compounds, the angles between the planes of the two π-ligands are 15.4 (2) and 16.4 (2)°, with gallium in a distorted tetrahedral coordination environment. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2960990/ /pubmed/21201986 http://dx.doi.org/10.1107/S1600536808005503 Text en © Schachner et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Schachner, Jörg A. Quail, J. Wilson Müller, Jens The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2) C,N}(ferrocene-1,1′-diyl)gallium(III) |
| title | The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2)
C,N}(ferrocene-1,1′-diyl)gallium(III) |
| title_full | The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2)
C,N}(ferrocene-1,1′-diyl)gallium(III) |
| title_fullStr | The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2)
C,N}(ferrocene-1,1′-diyl)gallium(III) |
| title_full_unstemmed | The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2)
C,N}(ferrocene-1,1′-diyl)gallium(III) |
| title_short | The galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2)
C,N}(ferrocene-1,1′-diyl)gallium(III) |
| title_sort | galla[1]ferrocenophane {[dimethyl(2-pyridyl)silyl]bis(trimethylsilyl)methyl-κ(2)
c,n}(ferrocene-1,1′-diyl)gallium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960990/ https://www.ncbi.nlm.nih.gov/pubmed/21201986 http://dx.doi.org/10.1107/S1600536808005503 |
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