Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate

In the title compound, [CuCl(2)(C(14)H(12)N(4))(2)]·3.33H(2)O, the Cu(II) atom is coordinated by two chelating 3-methyl-4-phenyl-5-(2-pyrid­yl)-1,2,4-triazole ligands and two chloride anions in a distorted octa­hedral geometry with a CuN(2)N(′) (2)Cl(2) chromophore. The Cu atom is located on an inve...

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Detalles Bibliográficos
Autores principales: Wang, Zuoxiang, Lan, Yan, Wu, Pingfeng, Huang, Liaocheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960994/
https://www.ncbi.nlm.nih.gov/pubmed/21202040
http://dx.doi.org/10.1107/S1600536808007630
Descripción
Sumario:In the title compound, [CuCl(2)(C(14)H(12)N(4))(2)]·3.33H(2)O, the Cu(II) atom is coordinated by two chelating 3-methyl-4-phenyl-5-(2-pyrid­yl)-1,2,4-triazole ligands and two chloride anions in a distorted octa­hedral geometry with a CuN(2)N(′) (2)Cl(2) chromophore. The Cu atom is located on an inversion center. Two uncoordinated water mol­ecules lie on threefold rotation axes with disordered H atoms. Two hydrogen bonds are formed between the water mol­ecules, and another between water and a chlorido ligand.

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