Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate

In the title compound, [CuCl(2)(C(14)H(12)N(4))(2)]·3.33H(2)O, the Cu(II) atom is coordinated by two chelating 3-methyl-4-phenyl-5-(2-pyrid­yl)-1,2,4-triazole ligands and two chloride anions in a distorted octa­hedral geometry with a CuN(2)N(′) (2)Cl(2) chromophore. The Cu atom is located on an inve...

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Detalles Bibliográficos
Autores principales: Wang, Zuoxiang, Lan, Yan, Wu, Pingfeng, Huang, Liaocheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960994/
https://www.ncbi.nlm.nih.gov/pubmed/21202040
http://dx.doi.org/10.1107/S1600536808007630
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author Wang, Zuoxiang
Lan, Yan
Wu, Pingfeng
Huang, Liaocheng
author_facet Wang, Zuoxiang
Lan, Yan
Wu, Pingfeng
Huang, Liaocheng
author_sort Wang, Zuoxiang
collection PubMed
description In the title compound, [CuCl(2)(C(14)H(12)N(4))(2)]·3.33H(2)O, the Cu(II) atom is coordinated by two chelating 3-methyl-4-phenyl-5-(2-pyrid­yl)-1,2,4-triazole ligands and two chloride anions in a distorted octa­hedral geometry with a CuN(2)N(′) (2)Cl(2) chromophore. The Cu atom is located on an inversion center. Two uncoordinated water mol­ecules lie on threefold rotation axes with disordered H atoms. Two hydrogen bonds are formed between the water mol­ecules, and another between water and a chlorido ligand.
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spelling pubmed-29609942010-12-30 Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate Wang, Zuoxiang Lan, Yan Wu, Pingfeng Huang, Liaocheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(14)H(12)N(4))(2)]·3.33H(2)O, the Cu(II) atom is coordinated by two chelating 3-methyl-4-phenyl-5-(2-pyrid­yl)-1,2,4-triazole ligands and two chloride anions in a distorted octa­hedral geometry with a CuN(2)N(′) (2)Cl(2) chromophore. The Cu atom is located on an inversion center. Two uncoordinated water mol­ecules lie on threefold rotation axes with disordered H atoms. Two hydrogen bonds are formed between the water mol­ecules, and another between water and a chlorido ligand. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960994/ /pubmed/21202040 http://dx.doi.org/10.1107/S1600536808007630 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zuoxiang
Lan, Yan
Wu, Pingfeng
Huang, Liaocheng
Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate
title Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate
title_full Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate
title_fullStr Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate
title_full_unstemmed Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate
title_short Dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) 3.33-hydrate
title_sort dichloridobis[3-methyl-4-phenyl-5-(2-pyrid­yl)-4h-1,2,4-triazole-κ(2) n (1),n (5)]copper(ii) 3.33-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960994/
https://www.ncbi.nlm.nih.gov/pubmed/21202040
http://dx.doi.org/10.1107/S1600536808007630
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