(1R,2R)-N,N′-Dimethyl­cyclo­hexane-1,2-diamine

The molecule of the title compound, C(8)H(18)N(2), possesses C (2) symmetry. Owing to its stereochemistry, it is used in the synthesis of chiral ligands and metal complexes for asymmetric synthesis. The cyclo­hexane ring shows a chair conformation with the amino groups in equatorial positions. Contr...

Descripción completa

Detalles Bibliográficos
Autores principales: Strohmann, Carsten, Gessner, Viktoria H., Damme, Alexander, Koller, Stephan, Däschlein, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960996/
https://www.ncbi.nlm.nih.gov/pubmed/21202079
http://dx.doi.org/10.1107/S1600536808006119
_version_ 1782188876006162432
author Strohmann, Carsten
Gessner, Viktoria H.
Damme, Alexander
Koller, Stephan
Däschlein, Christian
author_facet Strohmann, Carsten
Gessner, Viktoria H.
Damme, Alexander
Koller, Stephan
Däschlein, Christian
author_sort Strohmann, Carsten
collection PubMed
description The molecule of the title compound, C(8)H(18)N(2), possesses C (2) symmetry. Owing to its stereochemistry, it is used in the synthesis of chiral ligands and metal complexes for asymmetric synthesis. The cyclo­hexane ring shows a chair conformation with the amino groups in equatorial positions. Contrary to the literature, the title compound is not a liquid, but a crystalline solid at room temperature (293 K). The absolute configuration is assigned from the synthesis.
format Text
id pubmed-2960996
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29609962010-12-30 (1R,2R)-N,N′-Dimethyl­cyclo­hexane-1,2-diamine Strohmann, Carsten Gessner, Viktoria H. Damme, Alexander Koller, Stephan Däschlein, Christian Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(8)H(18)N(2), possesses C (2) symmetry. Owing to its stereochemistry, it is used in the synthesis of chiral ligands and metal complexes for asymmetric synthesis. The cyclo­hexane ring shows a chair conformation with the amino groups in equatorial positions. Contrary to the literature, the title compound is not a liquid, but a crystalline solid at room temperature (293 K). The absolute configuration is assigned from the synthesis. International Union of Crystallography 2008-03-12 /pmc/articles/PMC2960996/ /pubmed/21202079 http://dx.doi.org/10.1107/S1600536808006119 Text en © Strohmann et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Strohmann, Carsten
Gessner, Viktoria H.
Damme, Alexander
Koller, Stephan
Däschlein, Christian
(1R,2R)-N,N′-Dimethyl­cyclo­hexane-1,2-diamine
title (1R,2R)-N,N′-Dimethyl­cyclo­hexane-1,2-diamine
title_full (1R,2R)-N,N′-Dimethyl­cyclo­hexane-1,2-diamine
title_fullStr (1R,2R)-N,N′-Dimethyl­cyclo­hexane-1,2-diamine
title_full_unstemmed (1R,2R)-N,N′-Dimethyl­cyclo­hexane-1,2-diamine
title_short (1R,2R)-N,N′-Dimethyl­cyclo­hexane-1,2-diamine
title_sort (1r,2r)-n,n′-dimethyl­cyclo­hexane-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960996/
https://www.ncbi.nlm.nih.gov/pubmed/21202079
http://dx.doi.org/10.1107/S1600536808006119
work_keys_str_mv AT strohmanncarsten 1r2rnndimethylcyclohexane12diamine
AT gessnerviktoriah 1r2rnndimethylcyclohexane12diamine
AT dammealexander 1r2rnndimethylcyclohexane12diamine
AT kollerstephan 1r2rnndimethylcyclohexane12diamine
AT daschleinchristian 1r2rnndimethylcyclohexane12diamine

Ejemplares similares