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Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)]
In the title centrosymmetric dinuclear compound, [Cu(2)(C(8)H(7)O(2))(4)(C(8)H(8)O(2))(2)], four o-toluate anions form a cage around two Cu atoms in a syn–syn configuration. Two more o-toluic acid molecules are apically bonded to the Cu atoms, which show a square-pyramidal coordination geometry. Th...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960998/ https://www.ncbi.nlm.nih.gov/pubmed/21202010 http://dx.doi.org/10.1107/S1600536808006661 |
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| author | Sunil, Abraham C. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus |
| author_facet | Sunil, Abraham C. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus |
| author_sort | Sunil, Abraham C. |
| collection | PubMed |
| description | In the title centrosymmetric dinuclear compound, [Cu(2)(C(8)H(7)O(2))(4)(C(8)H(8)O(2))(2)], four o-toluate anions form a cage around two Cu atoms in a syn–syn configuration. Two more o-toluic acid molecules are apically bonded to the Cu atoms, which show a square-pyramidal coordination geometry. The acid H atoms are hydrogen bonded to the cage carboxyl O atoms [O⋯O = 2.660 (2) Å]. The molecular packing forms a puckered pseudo-hexagonal close-packed layer in the (h00) plane, with soft intermolecular H⋯H contacts (2.46–2.58 Å). |
| format | Text |
| id | pubmed-2960998 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29609982010-12-30 Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)] Sunil, Abraham C. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric dinuclear compound, [Cu(2)(C(8)H(7)O(2))(4)(C(8)H(8)O(2))(2)], four o-toluate anions form a cage around two Cu atoms in a syn–syn configuration. Two more o-toluic acid molecules are apically bonded to the Cu atoms, which show a square-pyramidal coordination geometry. The acid H atoms are hydrogen bonded to the cage carboxyl O atoms [O⋯O = 2.660 (2) Å]. The molecular packing forms a puckered pseudo-hexagonal close-packed layer in the (h00) plane, with soft intermolecular H⋯H contacts (2.46–2.58 Å). International Union of Crystallography 2008-03-14 /pmc/articles/PMC2960998/ /pubmed/21202010 http://dx.doi.org/10.1107/S1600536808006661 Text en © Sunil et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sunil, Abraham C. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)] |
| title | Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)] |
| title_full | Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)] |
| title_fullStr | Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)] |
| title_full_unstemmed | Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)] |
| title_short | Tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(II)] |
| title_sort | tetrakis(μ-2-methylbenzoato)bis[(2-methylbenzoic acid)copper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960998/ https://www.ncbi.nlm.nih.gov/pubmed/21202010 http://dx.doi.org/10.1107/S1600536808006661 |
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