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cis-Bis(2,2′-bipyridyl)dicyanatocobalt(II)
In the title complex, [Co(NCO)(2)(C(10)H(8)N(2))(2)], the Co atom is coordinated by four N atoms from two 2,2′-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octahedral geometry. The Co atom lies on a twofold rotation axis. The average Co—N bond length is 2.126 (7) Å. Weak...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960999/ https://www.ncbi.nlm.nih.gov/pubmed/21202031 http://dx.doi.org/10.1107/S1600536808007617 |
| Sumario: | In the title complex, [Co(NCO)(2)(C(10)H(8)N(2))(2)], the Co atom is coordinated by four N atoms from two 2,2′-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octahedral geometry. The Co atom lies on a twofold rotation axis. The average Co—N bond length is 2.126 (7) Å. Weak intermolecular C—H⋯O interactions lead to the formation of a three-dimensional network. |
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