cis-Bis­(2,2′-bipyrid­yl)dicyanato­cobalt(II)

In the title complex, [Co(NCO)(2)(C(10)H(8)N(2))(2)], the Co atom is coordinated by four N atoms from two 2,2′-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octa­hedral geometry. The Co atom lies on a twofold rotation axis. The average Co—N bond length is 2.126 (7) Å. Weak...

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Detalles Bibliográficos
Autores principales: Jia, LI, Kong, Ling-Qian, Li, Da-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960999/
https://www.ncbi.nlm.nih.gov/pubmed/21202031
http://dx.doi.org/10.1107/S1600536808007617
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author Jia, LI
Kong, Ling-Qian
Li, Da-Cheng
author_facet Jia, LI
Kong, Ling-Qian
Li, Da-Cheng
author_sort Jia, LI
collection PubMed
description In the title complex, [Co(NCO)(2)(C(10)H(8)N(2))(2)], the Co atom is coordinated by four N atoms from two 2,2′-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octa­hedral geometry. The Co atom lies on a twofold rotation axis. The average Co—N bond length is 2.126 (7) Å. Weak inter­molecular C—H⋯O inter­actions lead to the formation of a three-dimensional network.
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spelling pubmed-29609992010-12-30 cis-Bis­(2,2′-bipyrid­yl)dicyanato­cobalt(II) Jia, LI Kong, Ling-Qian Li, Da-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(NCO)(2)(C(10)H(8)N(2))(2)], the Co atom is coordinated by four N atoms from two 2,2′-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octa­hedral geometry. The Co atom lies on a twofold rotation axis. The average Co—N bond length is 2.126 (7) Å. Weak inter­molecular C—H⋯O inter­actions lead to the formation of a three-dimensional network. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2960999/ /pubmed/21202031 http://dx.doi.org/10.1107/S1600536808007617 Text en © Jia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jia, LI
Kong, Ling-Qian
Li, Da-Cheng
cis-Bis­(2,2′-bipyrid­yl)dicyanato­cobalt(II)
title cis-Bis­(2,2′-bipyrid­yl)dicyanato­cobalt(II)
title_full cis-Bis­(2,2′-bipyrid­yl)dicyanato­cobalt(II)
title_fullStr cis-Bis­(2,2′-bipyrid­yl)dicyanato­cobalt(II)
title_full_unstemmed cis-Bis­(2,2′-bipyrid­yl)dicyanato­cobalt(II)
title_short cis-Bis­(2,2′-bipyrid­yl)dicyanato­cobalt(II)
title_sort cis-bis­(2,2′-bipyrid­yl)dicyanato­cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960999/
https://www.ncbi.nlm.nih.gov/pubmed/21202031
http://dx.doi.org/10.1107/S1600536808007617
work_keys_str_mv AT jiali cisbis22bipyridyldicyanatocobaltii
AT konglingqian cisbis22bipyridyldicyanatocobaltii
AT lidacheng cisbis22bipyridyldicyanatocobaltii

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