(E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime

The title compound, C(10)H(10)N(2)O(2), was synthesized by the reaction of the oxime of 2-acetyl­pyridine and 3-bromo­propanoyl chloride in the presence of triethyl­amine. The mol­ecule adopts a nearly planar chain-extended conformation with the oxime group in a trans and the acryloyl group in an s-...

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Detalles Bibliográficos
Autores principales: Mojzych, Mariusz, Karczmarzyk, Zbigniew, Fruziński, Andrzej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961001/
https://www.ncbi.nlm.nih.gov/pubmed/21202050
http://dx.doi.org/10.1107/S1600536808005436
Descripción
Sumario:The title compound, C(10)H(10)N(2)O(2), was synthesized by the reaction of the oxime of 2-acetyl­pyridine and 3-bromo­propanoyl chloride in the presence of triethyl­amine. The mol­ecule adopts a nearly planar chain-extended conformation with the oxime group in a trans and the acryloyl group in an s-cis conformation. This conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond. The screw-related mol­ecules are linked into C(9) chains by C—H⋯O hydrogen bonds.

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