(E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime

The title compound, C(10)H(10)N(2)O(2), was synthesized by the reaction of the oxime of 2-acetyl­pyridine and 3-bromo­propanoyl chloride in the presence of triethyl­amine. The mol­ecule adopts a nearly planar chain-extended conformation with the oxime group in a trans and the acryloyl group in an s-...

Descripción completa

Detalles Bibliográficos
Autores principales: Mojzych, Mariusz, Karczmarzyk, Zbigniew, Fruziński, Andrzej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961001/
https://www.ncbi.nlm.nih.gov/pubmed/21202050
http://dx.doi.org/10.1107/S1600536808005436
_version_ 1782188877204684800
author Mojzych, Mariusz
Karczmarzyk, Zbigniew
Fruziński, Andrzej
author_facet Mojzych, Mariusz
Karczmarzyk, Zbigniew
Fruziński, Andrzej
author_sort Mojzych, Mariusz
collection PubMed
description The title compound, C(10)H(10)N(2)O(2), was synthesized by the reaction of the oxime of 2-acetyl­pyridine and 3-bromo­propanoyl chloride in the presence of triethyl­amine. The mol­ecule adopts a nearly planar chain-extended conformation with the oxime group in a trans and the acryloyl group in an s-cis conformation. This conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond. The screw-related mol­ecules are linked into C(9) chains by C—H⋯O hydrogen bonds.
format Text
id pubmed-2961001
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29610012010-12-30 (E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime Mojzych, Mariusz Karczmarzyk, Zbigniew Fruziński, Andrzej Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(10)N(2)O(2), was synthesized by the reaction of the oxime of 2-acetyl­pyridine and 3-bromo­propanoyl chloride in the presence of triethyl­amine. The mol­ecule adopts a nearly planar chain-extended conformation with the oxime group in a trans and the acryloyl group in an s-cis conformation. This conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond. The screw-related mol­ecules are linked into C(9) chains by C—H⋯O hydrogen bonds. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2961001/ /pubmed/21202050 http://dx.doi.org/10.1107/S1600536808005436 Text en © Mojzych et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mojzych, Mariusz
Karczmarzyk, Zbigniew
Fruziński, Andrzej
(E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime
title (E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime
title_full (E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime
title_fullStr (E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime
title_full_unstemmed (E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime
title_short (E)-1-(Pyridin-2-yl)ethanone O-acryloyloxime
title_sort (e)-1-(pyridin-2-yl)ethanone o-acryloyloxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961001/
https://www.ncbi.nlm.nih.gov/pubmed/21202050
http://dx.doi.org/10.1107/S1600536808005436
work_keys_str_mv AT mojzychmariusz e1pyridin2ylethanoneoacryloyloxime
AT karczmarzykzbigniew e1pyridin2ylethanoneoacryloyloxime
AT fruzinskiandrzej e1pyridin2ylethanoneoacryloyloxime

Ejemplares similares