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Hexaaqua­zinc(II) dipicrate

In the title compound, [Zn(H(2)O)(6)](C(6)H(2)N(3)O(7))(2), the Zn(II) ion is located on an inversion center and is coordinated by six water mol­ecules in an octa­hedral geometry. The picrate anions have no coordination inter­actions with the Zn(II) atom. The three nitro groups are twisted away from...

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Autores principales: Natarajan, S., Vijitha, K. V., Dhas, S. A. Martin Britto, Suresh, J., Lakshman, P. L. Nilantha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961002/
https://www.ncbi.nlm.nih.gov/pubmed/21202030
http://dx.doi.org/10.1107/S1600536808006624
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author Natarajan, S.
Vijitha, K. V.
Dhas, S. A. Martin Britto
Suresh, J.
Lakshman, P. L. Nilantha
author_facet Natarajan, S.
Vijitha, K. V.
Dhas, S. A. Martin Britto
Suresh, J.
Lakshman, P. L. Nilantha
author_sort Natarajan, S.
collection PubMed
description In the title compound, [Zn(H(2)O)(6)](C(6)H(2)N(3)O(7))(2), the Zn(II) ion is located on an inversion center and is coordinated by six water mol­ecules in an octa­hedral geometry. The picrate anions have no coordination inter­actions with the Zn(II) atom. The three nitro groups are twisted away from the attached benzene ring by19.8 (3), 6.5 (4) and 28.6 (3)°. There are numerous O—H⋯O hydrogen bonds in the crystal structure.
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spelling pubmed-29610022010-12-30 Hexaaqua­zinc(II) dipicrate Natarajan, S. Vijitha, K. V. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(H(2)O)(6)](C(6)H(2)N(3)O(7))(2), the Zn(II) ion is located on an inversion center and is coordinated by six water mol­ecules in an octa­hedral geometry. The picrate anions have no coordination inter­actions with the Zn(II) atom. The three nitro groups are twisted away from the attached benzene ring by19.8 (3), 6.5 (4) and 28.6 (3)°. There are numerous O—H⋯O hydrogen bonds in the crystal structure. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2961002/ /pubmed/21202030 http://dx.doi.org/10.1107/S1600536808006624 Text en © Natarajan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Natarajan, S.
Vijitha, K. V.
Dhas, S. A. Martin Britto
Suresh, J.
Lakshman, P. L. Nilantha
Hexaaqua­zinc(II) dipicrate
title Hexaaqua­zinc(II) dipicrate
title_full Hexaaqua­zinc(II) dipicrate
title_fullStr Hexaaqua­zinc(II) dipicrate
title_full_unstemmed Hexaaqua­zinc(II) dipicrate
title_short Hexaaqua­zinc(II) dipicrate
title_sort hexaaqua­zinc(ii) dipicrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961002/
https://www.ncbi.nlm.nih.gov/pubmed/21202030
http://dx.doi.org/10.1107/S1600536808006624
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