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Hexaaquazinc(II) dipicrate
In the title compound, [Zn(H(2)O)(6)](C(6)H(2)N(3)O(7))(2), the Zn(II) ion is located on an inversion center and is coordinated by six water molecules in an octahedral geometry. The picrate anions have no coordination interactions with the Zn(II) atom. The three nitro groups are twisted away from...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961002/ https://www.ncbi.nlm.nih.gov/pubmed/21202030 http://dx.doi.org/10.1107/S1600536808006624 |
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author | Natarajan, S. Vijitha, K. V. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha |
author_facet | Natarajan, S. Vijitha, K. V. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha |
author_sort | Natarajan, S. |
collection | PubMed |
description | In the title compound, [Zn(H(2)O)(6)](C(6)H(2)N(3)O(7))(2), the Zn(II) ion is located on an inversion center and is coordinated by six water molecules in an octahedral geometry. The picrate anions have no coordination interactions with the Zn(II) atom. The three nitro groups are twisted away from the attached benzene ring by19.8 (3), 6.5 (4) and 28.6 (3)°. There are numerous O—H⋯O hydrogen bonds in the crystal structure. |
format | Text |
id | pubmed-2961002 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29610022010-12-30 Hexaaquazinc(II) dipicrate Natarajan, S. Vijitha, K. V. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(H(2)O)(6)](C(6)H(2)N(3)O(7))(2), the Zn(II) ion is located on an inversion center and is coordinated by six water molecules in an octahedral geometry. The picrate anions have no coordination interactions with the Zn(II) atom. The three nitro groups are twisted away from the attached benzene ring by19.8 (3), 6.5 (4) and 28.6 (3)°. There are numerous O—H⋯O hydrogen bonds in the crystal structure. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2961002/ /pubmed/21202030 http://dx.doi.org/10.1107/S1600536808006624 Text en © Natarajan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Natarajan, S. Vijitha, K. V. Dhas, S. A. Martin Britto Suresh, J. Lakshman, P. L. Nilantha Hexaaquazinc(II) dipicrate |
title | Hexaaquazinc(II) dipicrate |
title_full | Hexaaquazinc(II) dipicrate |
title_fullStr | Hexaaquazinc(II) dipicrate |
title_full_unstemmed | Hexaaquazinc(II) dipicrate |
title_short | Hexaaquazinc(II) dipicrate |
title_sort | hexaaquazinc(ii) dipicrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961002/ https://www.ncbi.nlm.nih.gov/pubmed/21202030 http://dx.doi.org/10.1107/S1600536808006624 |
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