Cargando…
[(E)-2-(3,5-Dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3) O,N,O′](dimethylformamide-κO)copper(II)
In the title complex, [Cu(C(16)H(11)Br(2)NO(4))(C(3)H(7)NO)](2), there are two unique molecules in the asymmetric unit. Each Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L (2−) [LH(2) = (E)-2-(3,5-dibromo-2-hydroxybenzylideneamino)-2-(4-hydroxyphenyl)aceti...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961003/ https://www.ncbi.nlm.nih.gov/pubmed/21202044 http://dx.doi.org/10.1107/S1600536808007915 |
_version_ | 1782188877685981184 |
---|---|
author | Tan, Ming-Xiong Chen, Zhen-Feng Neng, Zhou Liang, Hong |
author_facet | Tan, Ming-Xiong Chen, Zhen-Feng Neng, Zhou Liang, Hong |
author_sort | Tan, Ming-Xiong |
collection | PubMed |
description | In the title complex, [Cu(C(16)H(11)Br(2)NO(4))(C(3)H(7)NO)](2), there are two unique molecules in the asymmetric unit. Each Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L (2−) [LH(2) = (E)-2-(3,5-dibromo-2-hydroxybenzylideneamino)-2-(4-hydroxyphenyl)acetic acid] and the O atom of a dimethylformamide molecule to give a slightly distorted square-planar geometry. The two unique molecules form a dimer through weak C—H⋯O hydrogen bonds. In the dimer, the Cu⋯Cu distance is 3.712 (1) Å. In the crystal structure, molecules form a one-dimensional chain through C—H⋯O hydrogen bonds. These are further aggregated into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2961003 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29610032010-12-30 [(E)-2-(3,5-Dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3) O,N,O′](dimethylformamide-κO)copper(II) Tan, Ming-Xiong Chen, Zhen-Feng Neng, Zhou Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(16)H(11)Br(2)NO(4))(C(3)H(7)NO)](2), there are two unique molecules in the asymmetric unit. Each Cu(II) atom is coordinated by two O atoms and one N atom from the tridentate ligand L (2−) [LH(2) = (E)-2-(3,5-dibromo-2-hydroxybenzylideneamino)-2-(4-hydroxyphenyl)acetic acid] and the O atom of a dimethylformamide molecule to give a slightly distorted square-planar geometry. The two unique molecules form a dimer through weak C—H⋯O hydrogen bonds. In the dimer, the Cu⋯Cu distance is 3.712 (1) Å. In the crystal structure, molecules form a one-dimensional chain through C—H⋯O hydrogen bonds. These are further aggregated into a three-dimensional network by O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2961003/ /pubmed/21202044 http://dx.doi.org/10.1107/S1600536808007915 Text en © Tan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tan, Ming-Xiong Chen, Zhen-Feng Neng, Zhou Liang, Hong [(E)-2-(3,5-Dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3) O,N,O′](dimethylformamide-κO)copper(II) |
title | [(E)-2-(3,5-Dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3)
O,N,O′](dimethylformamide-κO)copper(II) |
title_full | [(E)-2-(3,5-Dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3)
O,N,O′](dimethylformamide-κO)copper(II) |
title_fullStr | [(E)-2-(3,5-Dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3)
O,N,O′](dimethylformamide-κO)copper(II) |
title_full_unstemmed | [(E)-2-(3,5-Dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3)
O,N,O′](dimethylformamide-κO)copper(II) |
title_short | [(E)-2-(3,5-Dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3)
O,N,O′](dimethylformamide-κO)copper(II) |
title_sort | [(e)-2-(3,5-dibromo-2-oxidobenzylideneamino)-3-(4-hydroxyphenyl)propionato-κ(3)
o,n,o′](dimethylformamide-κo)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961003/ https://www.ncbi.nlm.nih.gov/pubmed/21202044 http://dx.doi.org/10.1107/S1600536808007915 |
work_keys_str_mv | AT tanmingxiong e235dibromo2oxidobenzylideneamino34hydroxyphenylpropionatok3onodimethylformamidekocopperii AT chenzhenfeng e235dibromo2oxidobenzylideneamino34hydroxyphenylpropionatok3onodimethylformamidekocopperii AT nengzhou e235dibromo2oxidobenzylideneamino34hydroxyphenylpropionatok3onodimethylformamidekocopperii AT lianghong e235dibromo2oxidobenzylideneamino34hydroxyphenylpropionatok3onodimethylformamidekocopperii |