Ethyl 2-[(Z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate

In the title compound, C(23)H(19)ClN(2)O(3)S, the central pyrimidine ring is significantly puckered, assuming almost a screw boat conformation. In addition to the usual inter­molecular C—H⋯O hydrogen bonding, short intra­molecular C—H⋯S contacts and π–π stacking inter­actions [centroid–centroid dist...

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Detalles Bibliográficos
Autores principales: Jotani, Mukesh M., Baldaniya, Bharat B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961005/
https://www.ncbi.nlm.nih.gov/pubmed/21202129
http://dx.doi.org/10.1107/S1600536808007356
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author Jotani, Mukesh M.
Baldaniya, Bharat B.
author_facet Jotani, Mukesh M.
Baldaniya, Bharat B.
author_sort Jotani, Mukesh M.
collection PubMed
description In the title compound, C(23)H(19)ClN(2)O(3)S, the central pyrimidine ring is significantly puckered, assuming almost a screw boat conformation. In addition to the usual inter­molecular C—H⋯O hydrogen bonding, short intra­molecular C—H⋯S contacts and π–π stacking inter­actions [centroid–centroid distance = 3.762 (2) Å] contribute to the crystal packing.
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spelling pubmed-29610052010-12-30 Ethyl 2-[(Z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate Jotani, Mukesh M. Baldaniya, Bharat B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(19)ClN(2)O(3)S, the central pyrimidine ring is significantly puckered, assuming almost a screw boat conformation. In addition to the usual inter­molecular C—H⋯O hydrogen bonding, short intra­molecular C—H⋯S contacts and π–π stacking inter­actions [centroid–centroid distance = 3.762 (2) Å] contribute to the crystal packing. International Union of Crystallography 2008-03-29 /pmc/articles/PMC2961005/ /pubmed/21202129 http://dx.doi.org/10.1107/S1600536808007356 Text en © Jotani and Baldaniya 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jotani, Mukesh M.
Baldaniya, Bharat B.
Ethyl 2-[(Z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title Ethyl 2-[(Z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_full Ethyl 2-[(Z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_fullStr Ethyl 2-[(Z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_full_unstemmed Ethyl 2-[(Z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_short Ethyl 2-[(Z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
title_sort ethyl 2-[(z)-3-chloro­benzyl­idene]-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5h-1,3-thia­zolo[3,2-a]pyrimidine-6-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961005/
https://www.ncbi.nlm.nih.gov/pubmed/21202129
http://dx.doi.org/10.1107/S1600536808007356
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AT baldaniyabharatb ethyl2z3chlorobenzylidene7methyl3oxo5phenyl23dihydro5h13thiazolo32apyrimidine6carboxylate

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