Poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate]

In the title compound, {[Mn(C(14)H(16)N(5)O(3))(2)]·2H(2)O}(n), the Mn(II) atom (site symmetry [Image: see text]) exhibits a distorted trans-MnN(2)O(4) octa­hedral geometry defined by two monodentate N-bonded and two bidentate O,O′-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyr...

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Detalles Bibliográficos
Autores principales: Huang, Jing, Hu, Wei-Ping, An, Zhe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961022/
https://www.ncbi.nlm.nih.gov/pubmed/21202004
http://dx.doi.org/10.1107/S1600536808006533
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author Huang, Jing
Hu, Wei-Ping
An, Zhe
author_facet Huang, Jing
Hu, Wei-Ping
An, Zhe
author_sort Huang, Jing
collection PubMed
description In the title compound, {[Mn(C(14)H(16)N(5)O(3))(2)]·2H(2)O}(n), the Mn(II) atom (site symmetry [Image: see text]) exhibits a distorted trans-MnN(2)O(4) octa­hedral geometry defined by two monodentate N-bonded and two bidentate O,O′-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ate anions. An N—H⋯O hydrogen bond is present in the crystal structure. The extended two-dimensional structure is a square grid and the disordered uncoordinated water mol­ecules occupy cavities within the grid.
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spelling pubmed-29610222010-12-30 Poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate] Huang, Jing Hu, Wei-Ping An, Zhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(C(14)H(16)N(5)O(3))(2)]·2H(2)O}(n), the Mn(II) atom (site symmetry [Image: see text]) exhibits a distorted trans-MnN(2)O(4) octa­hedral geometry defined by two monodentate N-bonded and two bidentate O,O′-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ate anions. An N—H⋯O hydrogen bond is present in the crystal structure. The extended two-dimensional structure is a square grid and the disordered uncoordinated water mol­ecules occupy cavities within the grid. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2961022/ /pubmed/21202004 http://dx.doi.org/10.1107/S1600536808006533 Text en © Huang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Jing
Hu, Wei-Ping
An, Zhe
Poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate]
title Poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate]
title_full Poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate]
title_fullStr Poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate]
title_full_unstemmed Poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate]
title_short Poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(II)] dihydrate]
title_sort poly[[bis­[μ(2)-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydro­pyrido[2,3-d]pyrimidine-6-carboxyl­ato]manganese(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961022/
https://www.ncbi.nlm.nih.gov/pubmed/21202004
http://dx.doi.org/10.1107/S1600536808006533
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AT huweiping polybism28ethyl5oxo2piperazin1yl58dihydropyrido23dpyrimidine6carboxylatomanganeseiidihydrate
AT anzhe polybism28ethyl5oxo2piperazin1yl58dihydropyrido23dpyrimidine6carboxylatomanganeseiidihydrate

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