Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]zinc(II)

In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra­hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol­ecules are connected by weak C—H⋯S inter­molecu...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Tarafder, M. T. H., Islam, M. Toihidul, Zakaria, C. M., Islam, M. A. A. A. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961027/
https://www.ncbi.nlm.nih.gov/pubmed/21201987
http://dx.doi.org/10.1107/S1600536808005643
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author Fun, Hoong-Kun
Chantrapromma, Suchada
Tarafder, M. T. H.
Islam, M. Toihidul
Zakaria, C. M.
Islam, M. A. A. A. A.
author_facet Fun, Hoong-Kun
Chantrapromma, Suchada
Tarafder, M. T. H.
Islam, M. Toihidul
Zakaria, C. M.
Islam, M. A. A. A. A.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra­hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol­ecules are connected by weak C—H⋯S inter­molecular inter­actions into chains along the c axis. The crystal structure is further stabilized by C—H⋯π inter­actions involving the phenyl ring of the 3-phenyl­prop-2-enyl­idene unit.
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spelling pubmed-29610272010-12-30 Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]zinc(II) Fun, Hoong-Kun Chantrapromma, Suchada Tarafder, M. T. H. Islam, M. Toihidul Zakaria, C. M. Islam, M. A. A. A. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra­hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol­ecules are connected by weak C—H⋯S inter­molecular inter­actions into chains along the c axis. The crystal structure is further stabilized by C—H⋯π inter­actions involving the phenyl ring of the 3-phenyl­prop-2-enyl­idene unit. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2961027/ /pubmed/21201987 http://dx.doi.org/10.1107/S1600536808005643 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fun, Hoong-Kun
Chantrapromma, Suchada
Tarafder, M. T. H.
Islam, M. Toihidul
Zakaria, C. M.
Islam, M. A. A. A. A.
Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]zinc(II)
title Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]zinc(II)
title_full Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]zinc(II)
title_fullStr Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]zinc(II)
title_full_unstemmed Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]zinc(II)
title_short Bis[benzyl N′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) N′,S]zinc(II)
title_sort bis[benzyl n′-(3-phenyl­prop-2-enyl­idene)hydrazinecarbodithio­ato-κ(2) n′,s]zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961027/
https://www.ncbi.nlm.nih.gov/pubmed/21201987
http://dx.doi.org/10.1107/S1600536808005643
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