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[2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate
In the title compound, [Zn(C(14)H(9)O(4))(C(12)H(8)N(2))(2)](C(14)H(9)O(4))·H(2)O, the Zn(II) atom of the complex cation is six-coordinated in an octahedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxylate group from a singly deprotonated diphenic acid...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961034/ https://www.ncbi.nlm.nih.gov/pubmed/21201991 http://dx.doi.org/10.1107/S1600536808005862 |
| _version_ | 1782188885084733440 |
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| author | Huang, Wei-Wei Yang, Shi-Ping |
| author_facet | Huang, Wei-Wei Yang, Shi-Ping |
| author_sort | Huang, Wei-Wei |
| collection | PubMed |
| description | In the title compound, [Zn(C(14)H(9)O(4))(C(12)H(8)N(2))(2)](C(14)H(9)O(4))·H(2)O, the Zn(II) atom of the complex cation is six-coordinated in an octahedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxylate group from a singly deprotonated diphenic acid. The phenanthroline and carboxylate ligands act as chelating ligands. The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)° (anion). O—H⋯O and C—H⋯O hydrogen bonds link the components into a three-dimensional network. |
| format | Text |
| id | pubmed-2961034 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29610342010-12-30 [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate Huang, Wei-Wei Yang, Shi-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(14)H(9)O(4))(C(12)H(8)N(2))(2)](C(14)H(9)O(4))·H(2)O, the Zn(II) atom of the complex cation is six-coordinated in an octahedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxylate group from a singly deprotonated diphenic acid. The phenanthroline and carboxylate ligands act as chelating ligands. The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)° (anion). O—H⋯O and C—H⋯O hydrogen bonds link the components into a three-dimensional network. International Union of Crystallography 2008-03-07 /pmc/articles/PMC2961034/ /pubmed/21201991 http://dx.doi.org/10.1107/S1600536808005862 Text en © Huang and Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Huang, Wei-Wei Yang, Shi-Ping [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_full | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_fullStr | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_full_unstemmed | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_short | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_sort | [2-(2-carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(ii) 2-(2-carboxyphenyl)benzoate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961034/ https://www.ncbi.nlm.nih.gov/pubmed/21201991 http://dx.doi.org/10.1107/S1600536808005862 |
| work_keys_str_mv | AT huangweiwei 22carboxyphenylbenzoatobis110phenanthrolinezincii22carboxyphenylbenzoatemonohydrate AT yangshiping 22carboxyphenylbenzoatobis110phenanthrolinezincii22carboxyphenylbenzoatemonohydrate |