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(2,2′-Bipyridine-κ(2) N,N′){[(3-methoxy-2-oxidobenzylidene-κO (2))hydrazono]methanolato-κ(2) N (2),O}dimethyltin(IV)
In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a pentagonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn—C, Sn—N and Sn—O are in the ranges 2.097 (3)–2.098 (3), 2.298 (2)...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961040/ https://www.ncbi.nlm.nih.gov/pubmed/21201994 http://dx.doi.org/10.1107/S1600536808006090 |
| _version_ | 1782188886620897280 |
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| author | Shuja, Shaukat Ali, Saqib Tahir, M. Nawaz Khalid, Nasir Khan, Islam Ullah |
| author_facet | Shuja, Shaukat Ali, Saqib Tahir, M. Nawaz Khalid, Nasir Khan, Islam Ullah |
| author_sort | Shuja, Shaukat |
| collection | PubMed |
| description | In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a pentagonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn—C, Sn—N and Sn—O are in the ranges 2.097 (3)–2.098 (3), 2.298 (2)–2.623 (2) and 2.157 (2)–2.266 (2) Å, respectively. The molecular structure of the monomeric compound is stabilized by three intramolecular C—H⋯O hydrogen bonds, all involving bipyridine C—H groups. |
| format | Text |
| id | pubmed-2961040 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29610402010-12-30 (2,2′-Bipyridine-κ(2) N,N′){[(3-methoxy-2-oxidobenzylidene-κO (2))hydrazono]methanolato-κ(2) N (2),O}dimethyltin(IV) Shuja, Shaukat Ali, Saqib Tahir, M. Nawaz Khalid, Nasir Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a pentagonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn—C, Sn—N and Sn—O are in the ranges 2.097 (3)–2.098 (3), 2.298 (2)–2.623 (2) and 2.157 (2)–2.266 (2) Å, respectively. The molecular structure of the monomeric compound is stabilized by three intramolecular C—H⋯O hydrogen bonds, all involving bipyridine C—H groups. International Union of Crystallography 2008-03-07 /pmc/articles/PMC2961040/ /pubmed/21201994 http://dx.doi.org/10.1107/S1600536808006090 Text en © Shuja et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shuja, Shaukat Ali, Saqib Tahir, M. Nawaz Khalid, Nasir Khan, Islam Ullah (2,2′-Bipyridine-κ(2) N,N′){[(3-methoxy-2-oxidobenzylidene-κO (2))hydrazono]methanolato-κ(2) N (2),O}dimethyltin(IV) |
| title | (2,2′-Bipyridine-κ(2)
N,N′){[(3-methoxy-2-oxidobenzylidene-κO
(2))hydrazono]methanolato-κ(2)
N
(2),O}dimethyltin(IV) |
| title_full | (2,2′-Bipyridine-κ(2)
N,N′){[(3-methoxy-2-oxidobenzylidene-κO
(2))hydrazono]methanolato-κ(2)
N
(2),O}dimethyltin(IV) |
| title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′){[(3-methoxy-2-oxidobenzylidene-κO
(2))hydrazono]methanolato-κ(2)
N
(2),O}dimethyltin(IV) |
| title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′){[(3-methoxy-2-oxidobenzylidene-κO
(2))hydrazono]methanolato-κ(2)
N
(2),O}dimethyltin(IV) |
| title_short | (2,2′-Bipyridine-κ(2)
N,N′){[(3-methoxy-2-oxidobenzylidene-κO
(2))hydrazono]methanolato-κ(2)
N
(2),O}dimethyltin(IV) |
| title_sort | (2,2′-bipyridine-κ(2)
n,n′){[(3-methoxy-2-oxidobenzylidene-κo
(2))hydrazono]methanolato-κ(2)
n
(2),o}dimethyltin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961040/ https://www.ncbi.nlm.nih.gov/pubmed/21201994 http://dx.doi.org/10.1107/S1600536808006090 |
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