Hexakis(1H-imidazole-κN (3))nickel(II) bis­(3-thienylacetate)

In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octa­hedral coordination geometry, defined by six N atoms from the imidazole ligands. Inter­molecular N—H⋯O hydrogen-bonding inter­actions between the cationic complex and 3-thienylacetate anions form a three-...

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Detalles Bibliográficos
Autores principales: Song, Wen-Dong, Ji, Li-Li, Wang, Hao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961043/
https://www.ncbi.nlm.nih.gov/pubmed/21202007
http://dx.doi.org/10.1107/S1600536808006363
Descripción
Sumario:In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octa­hedral coordination geometry, defined by six N atoms from the imidazole ligands. Inter­molecular N—H⋯O hydrogen-bonding inter­actions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture. The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5).

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