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Hexakis(1H-imidazole-κN (3))nickel(II) bis(3-thienylacetate)
In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octahedral coordination geometry, defined by six N atoms from the imidazole ligands. Intermolecular N—H⋯O hydrogen-bonding interactions between the cationic complex and 3-thienylacetate anions form a three-...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961043/ https://www.ncbi.nlm.nih.gov/pubmed/21202007 http://dx.doi.org/10.1107/S1600536808006363 |
| _version_ | 1782188887321346048 |
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| author | Song, Wen-Dong Ji, Li-Li Wang, Hao |
| author_facet | Song, Wen-Dong Ji, Li-Li Wang, Hao |
| author_sort | Song, Wen-Dong |
| collection | PubMed |
| description | In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octahedral coordination geometry, defined by six N atoms from the imidazole ligands. Intermolecular N—H⋯O hydrogen-bonding interactions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture. The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5). |
| format | Text |
| id | pubmed-2961043 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29610432010-12-30 Hexakis(1H-imidazole-κN (3))nickel(II) bis(3-thienylacetate) Song, Wen-Dong Ji, Li-Li Wang, Hao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(3)H(4)N(2))(6)](C(6)H(5)O(2)S)(2), the Ni(II) atom displays an octahedral coordination geometry, defined by six N atoms from the imidazole ligands. Intermolecular N—H⋯O hydrogen-bonding interactions between the cationic complex and 3-thienylacetate anions form a three-dimensional network architecture. The two 3-thienylacetate anions are disordered, with occupancy ratios of circa 0.774 (1):0.226 (1) and ca 0.753 (5):0.247 (5). International Union of Crystallography 2008-03-14 /pmc/articles/PMC2961043/ /pubmed/21202007 http://dx.doi.org/10.1107/S1600536808006363 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Song, Wen-Dong Ji, Li-Li Wang, Hao Hexakis(1H-imidazole-κN (3))nickel(II) bis(3-thienylacetate) |
| title | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(3-thienylacetate) |
| title_full | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(3-thienylacetate) |
| title_fullStr | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(3-thienylacetate) |
| title_full_unstemmed | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(3-thienylacetate) |
| title_short | Hexakis(1H-imidazole-κN
(3))nickel(II) bis(3-thienylacetate) |
| title_sort | hexakis(1h-imidazole-κn
(3))nickel(ii) bis(3-thienylacetate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961043/ https://www.ncbi.nlm.nih.gov/pubmed/21202007 http://dx.doi.org/10.1107/S1600536808006363 |
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