(Heptanedioato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)zinc(II) hexa­hydrate

In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl­ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta­nedioic acid) and four N atoms of two phenanthroline ligands, forming a conside...

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Detalles Bibliográficos
Autores principales: Lin, Jian-Li, Wang, Yuan-Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961045/
https://www.ncbi.nlm.nih.gov/pubmed/21201992
http://dx.doi.org/10.1107/S1600536808006004
Descripción
Sumario:In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl­ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta­nedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octa­hedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a three-dimensional network via C—H⋯O, C—H⋯π and π–π inter­actions. The mean inter­planar distance between adjacent phenanthroline ligands is 3.399 (2) Å.

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