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(Heptanedioato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) hexahydrate
In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxylate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is heptanedioic acid) and four N atoms of two phenanthroline ligands, forming a conside...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961045/ https://www.ncbi.nlm.nih.gov/pubmed/21201992 http://dx.doi.org/10.1107/S1600536808006004 |
| _version_ | 1782188887794253824 |
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| author | Lin, Jian-Li Wang, Yuan-Yuan |
| author_facet | Lin, Jian-Li Wang, Yuan-Yuan |
| author_sort | Lin, Jian-Li |
| collection | PubMed |
| description | In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxylate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is heptanedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octahedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a three-dimensional network via C—H⋯O, C—H⋯π and π–π interactions. The mean interplanar distance between adjacent phenanthroline ligands is 3.399 (2) Å. |
| format | Text |
| id | pubmed-2961045 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29610452010-12-30 (Heptanedioato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) hexahydrate Lin, Jian-Li Wang, Yuan-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxylate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is heptanedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octahedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a three-dimensional network via C—H⋯O, C—H⋯π and π–π interactions. The mean interplanar distance between adjacent phenanthroline ligands is 3.399 (2) Å. International Union of Crystallography 2008-03-07 /pmc/articles/PMC2961045/ /pubmed/21201992 http://dx.doi.org/10.1107/S1600536808006004 Text en © Lin and Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lin, Jian-Li Wang, Yuan-Yuan (Heptanedioato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)zinc(II) hexahydrate |
| title | (Heptanedioato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) hexahydrate |
| title_full | (Heptanedioato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) hexahydrate |
| title_fullStr | (Heptanedioato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) hexahydrate |
| title_full_unstemmed | (Heptanedioato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) hexahydrate |
| title_short | (Heptanedioato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) hexahydrate |
| title_sort | (heptanedioato-κ(2)
o,o′)bis(1,10-phenanthroline-κ(2)
n,n′)zinc(ii) hexahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961045/ https://www.ncbi.nlm.nih.gov/pubmed/21201992 http://dx.doi.org/10.1107/S1600536808006004 |
| work_keys_str_mv | AT linjianli heptanedioatok2oobis110phenanthrolinek2nnzinciihexahydrate AT wangyuanyuan heptanedioatok2oobis110phenanthrolinek2nnzinciihexahydrate |