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5,5′-Bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol
The title complex, C(26)H(38)N(4)O(4), was synthesized by the reaction of 4-diethylamino-2-hydroxybenzaldehyde with 1,4-bis(aminooxy)butane in ethanol. It crystallizes as discrete centrosymmetric molecules adopting an extended conformation where the two salicylaldoxime groups are separated from...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961048/ https://www.ncbi.nlm.nih.gov/pubmed/21202056 http://dx.doi.org/10.1107/S1600536808004352 |
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author | Liu, Gai-Lan Chen, Xiao He, Xue-Ni Dong, Wen-Kui |
author_facet | Liu, Gai-Lan Chen, Xiao He, Xue-Ni Dong, Wen-Kui |
author_sort | Liu, Gai-Lan |
collection | PubMed |
description | The title complex, C(26)H(38)N(4)O(4), was synthesized by the reaction of 4-diethylamino-2-hydroxybenzaldehyde with 1,4-bis(aminooxy)butane in ethanol. It crystallizes as discrete centrosymmetric molecules adopting an extended conformation where the two salicylaldoxime groups are separated from each other. Intramolecular O—H⋯N hydrogen bonding is observed between the hydroxy groups and oxime N atoms. Intermolecular π–π stacking interactions [3.979 (2) Å] between aromatic rings are apparent in the crystal structure. Each ethyl group is disordered over two positions; in one the site occupancy factors are 0.55 and 0.45, in the other 0.53 and 0.47. |
format | Text |
id | pubmed-2961048 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29610482010-12-30 5,5′-Bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol Liu, Gai-Lan Chen, Xiao He, Xue-Ni Dong, Wen-Kui Acta Crystallogr Sect E Struct Rep Online Organic Papers The title complex, C(26)H(38)N(4)O(4), was synthesized by the reaction of 4-diethylamino-2-hydroxybenzaldehyde with 1,4-bis(aminooxy)butane in ethanol. It crystallizes as discrete centrosymmetric molecules adopting an extended conformation where the two salicylaldoxime groups are separated from each other. Intramolecular O—H⋯N hydrogen bonding is observed between the hydroxy groups and oxime N atoms. Intermolecular π–π stacking interactions [3.979 (2) Å] between aromatic rings are apparent in the crystal structure. Each ethyl group is disordered over two positions; in one the site occupancy factors are 0.55 and 0.45, in the other 0.53 and 0.47. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2961048/ /pubmed/21202056 http://dx.doi.org/10.1107/S1600536808004352 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Liu, Gai-Lan Chen, Xiao He, Xue-Ni Dong, Wen-Kui 5,5′-Bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol |
title | 5,5′-Bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol |
title_full | 5,5′-Bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol |
title_fullStr | 5,5′-Bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol |
title_full_unstemmed | 5,5′-Bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol |
title_short | 5,5′-Bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol |
title_sort | 5,5′-bis(diethylamino)-2,2′-[butane-1,4-diyldioxybis(nitrilomethylidyne)]diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961048/ https://www.ncbi.nlm.nih.gov/pubmed/21202056 http://dx.doi.org/10.1107/S1600536808004352 |
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