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5,5′-Bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol

The title complex, C(26)H(38)N(4)O(4), was synthesized by the reaction of 4-diethyl­amino-2-hydroxy­benzaldehyde with 1,4-bis­(amino­oxy)butane in ethanol. It crystallizes as discrete centrosymmetric molecules adopting an extended conformation where the two salicylaldoxime groups are separated from...

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Detalles Bibliográficos
Autores principales: Liu, Gai-Lan, Chen, Xiao, He, Xue-Ni, Dong, Wen-Kui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961048/
https://www.ncbi.nlm.nih.gov/pubmed/21202056
http://dx.doi.org/10.1107/S1600536808004352
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author Liu, Gai-Lan
Chen, Xiao
He, Xue-Ni
Dong, Wen-Kui
author_facet Liu, Gai-Lan
Chen, Xiao
He, Xue-Ni
Dong, Wen-Kui
author_sort Liu, Gai-Lan
collection PubMed
description The title complex, C(26)H(38)N(4)O(4), was synthesized by the reaction of 4-diethyl­amino-2-hydroxy­benzaldehyde with 1,4-bis­(amino­oxy)butane in ethanol. It crystallizes as discrete centrosymmetric molecules adopting an extended conformation where the two salicylaldoxime groups are separated from each other. Intra­molecular O—H⋯N hydrogen bonding is observed between the hydr­oxy groups and oxime N atoms. Inter­molecular π–π stacking inter­actions [3.979 (2) Å] between aromatic rings are apparent in the crystal structure. Each ethyl group is disordered over two positions; in one the site occupancy factors are 0.55 and 0.45, in the other 0.53 and 0.47.
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spelling pubmed-29610482010-12-30 5,5′-Bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol Liu, Gai-Lan Chen, Xiao He, Xue-Ni Dong, Wen-Kui Acta Crystallogr Sect E Struct Rep Online Organic Papers The title complex, C(26)H(38)N(4)O(4), was synthesized by the reaction of 4-diethyl­amino-2-hydroxy­benzaldehyde with 1,4-bis­(amino­oxy)butane in ethanol. It crystallizes as discrete centrosymmetric molecules adopting an extended conformation where the two salicylaldoxime groups are separated from each other. Intra­molecular O—H⋯N hydrogen bonding is observed between the hydr­oxy groups and oxime N atoms. Inter­molecular π–π stacking inter­actions [3.979 (2) Å] between aromatic rings are apparent in the crystal structure. Each ethyl group is disordered over two positions; in one the site occupancy factors are 0.55 and 0.45, in the other 0.53 and 0.47. International Union of Crystallography 2008-03-05 /pmc/articles/PMC2961048/ /pubmed/21202056 http://dx.doi.org/10.1107/S1600536808004352 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Gai-Lan
Chen, Xiao
He, Xue-Ni
Dong, Wen-Kui
5,5′-Bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol
title 5,5′-Bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol
title_full 5,5′-Bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol
title_fullStr 5,5′-Bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol
title_full_unstemmed 5,5′-Bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol
title_short 5,5′-Bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol
title_sort 5,5′-bis(diethyl­amino)-2,2′-[butane-1,4-diyldioxy­bis(nitrilo­methyl­idyne)]­diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961048/
https://www.ncbi.nlm.nih.gov/pubmed/21202056
http://dx.doi.org/10.1107/S1600536808004352
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