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Aquabis(4-methylbenzoato)-κO;κ(2) O,O′-bis(pyridine-κN)nickel(II)
In the title mononuclear complex, [Ni(C(8)H(7)O(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Ni(II) atom is in a distorted octahedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methylbenzoate ligand and one monodentate 4-methylbenzoate ligand, two N atoms from pyridine ligand...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961051/ https://www.ncbi.nlm.nih.gov/pubmed/21202005 http://dx.doi.org/10.1107/S160053680800634X |
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author | Song, Wen-Dong Wang, Hao Ji, Li-Li |
author_facet | Song, Wen-Dong Wang, Hao Ji, Li-Li |
author_sort | Song, Wen-Dong |
collection | PubMed |
description | In the title mononuclear complex, [Ni(C(8)H(7)O(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Ni(II) atom is in a distorted octahedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methylbenzoate ligand and one monodentate 4-methylbenzoate ligand, two N atoms from pyridine ligands, axially positioned, and a water molecule. The equatorially positioned water molecule and uncoordinated carboxylate O atom form an intramolecular hydrogen bond. An intermolecular O—H⋯O hydrogen bond between the coordinated water molecule and carboxylate O atom of the 4-methylbenzoate ligand forms infinite chains along the b axis. These chains are connected by C—H⋯π interactions. |
format | Text |
id | pubmed-2961051 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29610512010-12-30 Aquabis(4-methylbenzoato)-κO;κ(2) O,O′-bis(pyridine-κN)nickel(II) Song, Wen-Dong Wang, Hao Ji, Li-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Ni(C(8)H(7)O(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Ni(II) atom is in a distorted octahedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methylbenzoate ligand and one monodentate 4-methylbenzoate ligand, two N atoms from pyridine ligands, axially positioned, and a water molecule. The equatorially positioned water molecule and uncoordinated carboxylate O atom form an intramolecular hydrogen bond. An intermolecular O—H⋯O hydrogen bond between the coordinated water molecule and carboxylate O atom of the 4-methylbenzoate ligand forms infinite chains along the b axis. These chains are connected by C—H⋯π interactions. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2961051/ /pubmed/21202005 http://dx.doi.org/10.1107/S160053680800634X Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Wen-Dong Wang, Hao Ji, Li-Li Aquabis(4-methylbenzoato)-κO;κ(2) O,O′-bis(pyridine-κN)nickel(II) |
title | Aquabis(4-methylbenzoato)-κO;κ(2)
O,O′-bis(pyridine-κN)nickel(II) |
title_full | Aquabis(4-methylbenzoato)-κO;κ(2)
O,O′-bis(pyridine-κN)nickel(II) |
title_fullStr | Aquabis(4-methylbenzoato)-κO;κ(2)
O,O′-bis(pyridine-κN)nickel(II) |
title_full_unstemmed | Aquabis(4-methylbenzoato)-κO;κ(2)
O,O′-bis(pyridine-κN)nickel(II) |
title_short | Aquabis(4-methylbenzoato)-κO;κ(2)
O,O′-bis(pyridine-κN)nickel(II) |
title_sort | aquabis(4-methylbenzoato)-κo;κ(2)
o,o′-bis(pyridine-κn)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961051/ https://www.ncbi.nlm.nih.gov/pubmed/21202005 http://dx.doi.org/10.1107/S160053680800634X |
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