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Aqua­bis(4-methyl­benzoato)-κO;κ(2) O,O′-bis­(pyridine-κN)nickel(II)

In the title mononuclear complex, [Ni(C(8)H(7)O(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Ni(II) atom is in a distorted octa­hedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methyl­benzoate ligand and one monodentate 4-methyl­benzoate ligand, two N atoms from pyridine ligand...

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Detalles Bibliográficos
Autores principales: Song, Wen-Dong, Wang, Hao, Ji, Li-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961051/
https://www.ncbi.nlm.nih.gov/pubmed/21202005
http://dx.doi.org/10.1107/S160053680800634X
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author Song, Wen-Dong
Wang, Hao
Ji, Li-Li
author_facet Song, Wen-Dong
Wang, Hao
Ji, Li-Li
author_sort Song, Wen-Dong
collection PubMed
description In the title mononuclear complex, [Ni(C(8)H(7)O(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Ni(II) atom is in a distorted octa­hedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methyl­benzoate ligand and one monodentate 4-methyl­benzoate ligand, two N atoms from pyridine ligands, axially positioned, and a water mol­ecule. The equatorially positioned water mol­ecule and uncoordinated carb­oxylate O atom form an intra­molecular hydrogen bond. An inter­molecular O—H⋯O hydrogen bond between the coordinated water mol­ecule and carboxylate O atom of the 4-methyl­benzoate ligand forms infinite chains along the b axis. These chains are connected by C—H⋯π inter­actions.
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spelling pubmed-29610512010-12-30 Aqua­bis(4-methyl­benzoato)-κO;κ(2) O,O′-bis­(pyridine-κN)nickel(II) Song, Wen-Dong Wang, Hao Ji, Li-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Ni(C(8)H(7)O(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Ni(II) atom is in a distorted octa­hedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methyl­benzoate ligand and one monodentate 4-methyl­benzoate ligand, two N atoms from pyridine ligands, axially positioned, and a water mol­ecule. The equatorially positioned water mol­ecule and uncoordinated carb­oxylate O atom form an intra­molecular hydrogen bond. An inter­molecular O—H⋯O hydrogen bond between the coordinated water mol­ecule and carboxylate O atom of the 4-methyl­benzoate ligand forms infinite chains along the b axis. These chains are connected by C—H⋯π inter­actions. International Union of Crystallography 2008-03-14 /pmc/articles/PMC2961051/ /pubmed/21202005 http://dx.doi.org/10.1107/S160053680800634X Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Wen-Dong
Wang, Hao
Ji, Li-Li
Aqua­bis(4-methyl­benzoato)-κO;κ(2) O,O′-bis­(pyridine-κN)nickel(II)
title Aqua­bis(4-methyl­benzoato)-κO;κ(2) O,O′-bis­(pyridine-κN)nickel(II)
title_full Aqua­bis(4-methyl­benzoato)-κO;κ(2) O,O′-bis­(pyridine-κN)nickel(II)
title_fullStr Aqua­bis(4-methyl­benzoato)-κO;κ(2) O,O′-bis­(pyridine-κN)nickel(II)
title_full_unstemmed Aqua­bis(4-methyl­benzoato)-κO;κ(2) O,O′-bis­(pyridine-κN)nickel(II)
title_short Aqua­bis(4-methyl­benzoato)-κO;κ(2) O,O′-bis­(pyridine-κN)nickel(II)
title_sort aqua­bis(4-methyl­benzoato)-κo;κ(2) o,o′-bis­(pyridine-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961051/
https://www.ncbi.nlm.nih.gov/pubmed/21202005
http://dx.doi.org/10.1107/S160053680800634X
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